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Novel CuInS-InSe QDs were prepared by a two stage organometallic colloidal synthesis procedure. A layer of indium selenide was grown over the CuInS QD core, under high temperature in the presence of oleylamine. The optical properties of the nanostructures grown were studied using UV-Vis absorption spectroscopy and the band gap obtained was in line with the cyclic voltammetry (CV) results. The elemental composition was analysed using energy dispersive X-ray spectroscopy (EDAX), inductive coupled plasma-atomic emission spectroscopy (ICP-AES) and X-ray photoelectron spectroscopy (XPS). The structural properties were investigated using X-ray diffraction (XRD) and high resolution transmission electron microscopy (HRTEM). The TEM images showed spherical nanostructures of size about 4.8 nm with well-defined lattice planes which were also evident from selected area electron diffraction (SAED) patterns. The XRD pattern indicated a tetragonal chalcopyrite crystal structure for the nanostructures.
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http://dx.doi.org/10.1039/c8ra07389a | DOI Listing |
Biosens Bioelectron
September 2025
College of Chemistry, Jilin Province Research Center for Engineering and Technology of Spectral Analytical Instruments, Jilin University, Qianjin Street 2699, Changchun, 130012, China. Electronic address:
Papillary thyroid carcinoma (PTC) is the most prevalent form of thyroid cancer with a high incidence among endocrine malignancies. It tends to metastasize early in lymph nodes and differs markedly from other subtypes in biological behavior, clinical management, and prognosis. Therefore, accurately distinguishing PTC from other pathological subtypes is crucial for guiding diagnosis and treatment decisions.
View Article and Find Full Text PDFNano Lett
September 2025
Center for 2D Quantum Heterostructures, Institute for Basic Science (IBS), Suwon 16419, Republic of Korea.
Ultrathin amorphous materials are promising counterparts to 2D crystalline materials, yet their properties and functionalities remain poorly understood. Amorphous boron nitride (aBN) has attracted attention for its ultralow dielectric constant and superior manufacturability compared with hexagonal boron nitride. Here, we demonstrate wafer-scale growth of ultrathin aBN films with exceptional thickness and composition uniformity using capacitively coupled plasma-chemical vapor deposition (CCP-CVD) at 400 °C.
View Article and Find Full Text PDFJ Phys Chem A
September 2025
Department of Chemistry, Institute for Quantum Information Research and Engineering, and Center for Molecular Quantum Transduction, Northwestern University, Evanston, Illinois 60208-3113, United States.
Light-driven formation of radical ion pairs that occurs much faster than their electron spin dynamics results in correlated spins whose coherence properties can be used as a quantum-based electric field sensor. This results from the radical ion pair having charge and spin distributions that track one another. Thus, electric field induced changes in the distance between the two charges are reflected in the spin-spin distance that can be measured directly using out-of-phase electron spin echo envelope modulation (OOP-ESEEM), a pulse-EPR technique.
View Article and Find Full Text PDFJ Phys Chem Lett
September 2025
School of Chemical Sciences, National Institute of Science Education and Research (NISER), An OCC of Homi Bhabha National Institute Jatni, Khurda, Bhubaneswar 752050, Odisha, India.
Quantum-confined perovskites represent an emerging class of materials with great potential for optoelectronic applications. Specifically, zero-dimensional (0D) perovskites have garnered significant attention for their unique excitonic properties. However, achieving phase-pure, size-tunable 0D perovskite materials and gaining a clear understanding of their photophysical behavior remains challenging.
View Article and Find Full Text PDFChem Rev
September 2025
Department of Physics, State Key Laboratory of Surface Physics, Fudan University, Shanghai 200438, P. R. China.
Diffusion is a fundamental process in the transfer of mass and energy. Diffusion metamaterials, a class of engineered materials with distinctive properties, enable precise control and manipulation of diffusion processes. Meanwhile, topology, a branch of mathematics, has attracted growing interest within the condensed matter physics community.
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