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Article Abstract
An active catalyst, [Cu]@Ag composite, was synthesized for the first time and used as a cathode for electrocarboxylation of cinnamyl chloride with CO. β,γ-Unsaturated carboxylic acids were obtained with excellent yield and moderate selectivity. Moreover, reasonable yields and selectivities of carboxylic acids were also achieved with several allylic halides and aryl halides.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9073196 | PMC |
| http://dx.doi.org/10.1039/c9ra05253d | DOI Listing |
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RSC Adv
October 2019
School of Chemistry and Molecular Engineering, East China Normal University Shanghai 200062 China +86-21-52134935 +86-21-62233491.
An active catalyst, [Cu]@Ag composite, was synthesized for the first time and used as a cathode for electrocarboxylation of cinnamyl chloride with CO. β,γ-Unsaturated carboxylic acids were obtained with excellent yield and moderate selectivity. Moreover, reasonable yields and selectivities of carboxylic acids were also achieved with several allylic halides and aryl halides.
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