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Objectives: To initially evaluate the outcomes of the modified triangular prismatic double-J (DJ) stent in the management of 2- to 3-cm renal stones after one-stage retrograde intrarenal surgery (RIRS).
Methods: Patients with 2- to 3-cm renal stones who underwent one-stage RIRS with indwelling DJ stents were retrospectively evaluated. Eighty-eight patients who were placed the triangular prismatic DJ stents and 64 patients who received standard DJ stents were randomly included. The clinical characteristics and intraoperative and postoperative outcomes of the 2 groups were compared and analyzed.
Results: The 2 groups had similar baseline characteristics. The urinary symptom score and pain score did not differ between groups (p > 0.05). The residual fragments of the 2 groups were similar 1 day after operation (p = 0.134). There was no significant difference in residual fragments in the lower calyx between groups at the time of stent removal (p = 0.834). The patients in the modified group had better spontaneous passage of residual fragments in the nonlower calyx than those in the standard group during the 2 weeks with the stents (p = 0.005). Fewer patients in the modified group had residual fragments (>4 mm) in the nonlower calyx (p = 0.026) and ureter (p = 0.010) than the patients with standard stents at the time of stent removal.
Conclusion: The indwelling triangular prismatic DJ stent is a safe and efficient treatment method. Patients with these stents had better spontaneous residual fragment passage than those with the standard DJ stents.
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http://dx.doi.org/10.1159/000512056 | DOI Listing |
PLoS One
August 2025
APSACA, National Center of Archeology, Tashkent, Uzbekistan.
Lithic weapon points occasionally found in Middle Palaeolithic Neanderthal sites are large and do not differ in size, shape or type from those used in other activities such as butchering or plant gathering. The presence in a same assemblage of various types of projectile armatures, some of which are microlithic and designed for this purpose, has only been documented in Modern Humans sites. Recent studies indicate that light projectile points, which would become a key element in Upper Palaeolithic lithic industries, were already present in its formative stages.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
June 2025
State Key Laboratory of Microbial Technology, Jiangsu Collaborative Innovation Center of Biomedical Functional Materials, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing, Jiangsu 210023, China.
The FeMo cofactor (FeMoco), the key active site in the Mo-based nitrogenase, is one of the most complicated metalloenzyme molecules. Synthesis of the FeMoco model cluster ([MoFeSC]) is essential to understanding its function in dinitrogen binding, activation, and conversion. However, the complex framework of the FeMoco cluster, which features a unique trigonal prismatic [FeC] moiety comprising a -bridging carbide, has made the synthesis of the cluster a persistent challenge.
View Article and Find Full Text PDFJ Am Chem Soc
June 2025
School of Chemistry and Chemical Engineering, Shandong University, Ji'nan 250100, People's Republic of China.
Smart molecular photoswitches are an important member in the realm of artificial materials, which can exhibit distinct physicochemical properties under photoirradiation, yet light-driven silver nanocluster switches have been scarcely exploited due to their intrinsic photoinstability. Herein, two photostable isostructural photoresponsive Ag nanoclusters ( and ) with a bicapped triangular prismatic Ag core protected by the ternary ligands of arylazopyrazole, aryl-thiolate, and diphosphine have been synthesized and characterized comprehensively. The introduction of arylazopyrazole augments a fresh functionality to the silver nanocluster, realizing photoisomerization switched photoluminescence.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
July 2025
Yusuf Hamied Department of Chemistry, University of Cambridge, Cambridge, CB2 1EW, U.K.
Herein we utilize the binding of fluoride to boron atoms to functionalize the interior of a boron-containing trigonal prismatic capsule that incorporates two triangular and three rectangular ligands, enabling the tuning of its guest binding properties. The methyl groups of the triangular ligands guide the rectangular ligands to adopt a "landscape" orientation to avoid steric hindrance. This small structural change gives rise to an enlarged interior cavity volume for guest encapsulation, as compared with a previously-reported trigonal prismatic capsule, where the same rectangular ligand took a "portrait" orientation with a non-methylated triangular ligand of similar size.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
July 2025
Frontier Institute of Science and Technology, Interdisciplinary Research Center of Frontier science and technology, State Key Laboratory of Electrical Insulation and Power Equipment, Xi'an Key Laboratory of Electronic Devices and Materials Chemistry, School of Chemical Engineering and Technology, In
Constructing cluster-based nodes and using them as catalytic sites can bring new structure and function for metal-organic cages (MOCs). However, successful examples are very limited. Herein, we found that a 2-mercapto-5-methyl-1,3,4-thiadiazole (Hmmt) based {Ni} subunit is robust in building such MOCs.
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