Category Ranking

98%

Total Visits

921

Avg Visit Duration

2 minutes

Citations

20

Article Abstract

Graphene is an ideal ultrathin material for various optoelectronic devices, but poor light-graphene interaction limits its further applications particularly in the visible (Vis) to near-infrared (NIR) region. Despite tremendous efforts to improve light absorption in graphene, achieving highly efficient light absorption of monolayer graphene within a comparatively simple architecture is still urgently needed. Here, we demonstrate the interesting attribute of bound state in the continuum (BIC) for highly efficient light absorption of graphene by using a simple Si-based photonic crystal slab (PCS) with a slit. Near-perfect absorption of monolayer graphene can be realized due to high confinement of light and near-field enhancement in the Si-based PCS, where BIC turns into quasi-BIC due to the symmetry-breaking of the structure. Theoretical analysis based on the coupled mode theory (CMT) is proposed to evaluate the absorption performances of monolayer graphene integrated with the symmetry-broken PCS, which indicates that high absorption of graphene is feasible at critical coupling based on the destructive interference of transmission light. Moreover, the absorption spectra of the monolayer graphene are stable to the variations of the structural parameters, and the angular tolerances of classical incidence can be effectively improved via full conical incidence. By using the full conical incidence, the angular bandwidths for the peak absorptivity and for the central wavelength of graphene absorption can be enhanced more than five times and 2.92 times, respectively. When the Si-based PCS with graphene is used in refractive index sensors, excellent sensing performances with sensitivity of 604 nm/RIU and figure of merit (FoM) of 151 can be achieved.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC7917831PMC
http://dx.doi.org/10.3390/nano11020484DOI Listing

Publication Analysis

Top Keywords

light absorption
20
monolayer graphene
20
highly efficient
12
efficient light
12
absorption monolayer
12
absorption graphene
12
graphene
11
absorption
9
state continuum
8
si-based pcs
8

Similar Publications

The electron-deficient oxidant 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) has recently emerged as a promising visible-light photoredox catalyst. However, its excited-state behavior remains poorly understood. Here, we investigate the ultrafast dynamics of photoexcited DDQ in acetonitrile using transient electronic and infrared absorption spectroscopy, supported by quantum chemical calculations.

View Article and Find Full Text PDF

Phycobilisome (PBS) is a water-soluble light-harvesting supercomplex found in cyanobacteria, glaucophytes, and rhodophytes. PBS interacts with photosynthetic reaction centers, specifically photosystems II and I (PSII and PSI), embedded in the thylakoid membrane. It is widely accepted that PBS predominantly associates with PSII, which functions as the initial complex in the linear electron transport chain.

View Article and Find Full Text PDF

Transient mixed-valent Ni active sites boost urea electrooxidation.

J Colloid Interface Sci

September 2025

Hefei National Research Center for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei 230026, China; Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, China. Electronic address:

The utilization of synergistic multivalent active sites holds potential in addressing the inherent sluggish kinetics of electrocatalytic reactions. Herein, we prepared au uNPs/Ni-NDC (NDC = 1,4-Naphthalenedicarboxylic acid) and leveraged the localized surface plasmon resonance (LSPR) effect to drive hot electron transfer from au nanoparticles to the Ni substrate, thereby generating multivalent active sites to boost the urea oxidation reaction (UOR). Under exciting light, au uNPs/Ni-NDC exhibited a twofold increase in UOR current accompanied by a significant negative shift in onset potential.

View Article and Find Full Text PDF

Synergistic interface and oxygen/nitrogen vacancy engineering in g-CN/CuO under high pressure for efficient CO photoreduction.

J Colloid Interface Sci

September 2025

WPI, International Institute for Carbon Neutral Energy Research (WPI-I2CNER), Kyushu University, Fukuoka 819-0395, Japan; Mitsui Chemicals, Inc -.Carbon Neutral Research Center (MCI-CNRC), Kyushu University, Fukuoka 819-0395, Japan. Electronic address:

This study explores highly active nitride-based g-CN/CuO photocatalysts for CO photoconversion by synthesizing them through high-pressure torsion (HPT) straining. Data indicate that increasing the applied strain under high pressure promotes vacancy formation and improves the electronic interaction at the g-CN/CuO interphases, enabling superior charge separation and extended light absorption. The generation of dual vacancies of oxygen and nitrogen is verified by electron paramagnetic resonance and Fourier transform infrared spectroscopic methods, and the generation of a type-II heterojunction is confirmed by band structure analysis.

View Article and Find Full Text PDF

Chitosan is a modified natural biopolymer obtained through the deacetylation of chitin, which is primarily found in the shells of crustaceans. Chitosan has recently attracted a lot of attention due to its possible use in the chemical, medical and food and industries. Due to its distinct biological activities and functional properties, its applications in the food industry are especially noteworthy.

View Article and Find Full Text PDF