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Article Abstract
Cucurbit[7]uril (CB7) catalyzes the hydrolysis reaction of bis(4-nitrophenyl)carbonate () but inhibits that of bis(4-nitrophenyl)thiocarbonate (). Two relevant CB7 effects are proposed, a base-catalyst mediated by the CB7 portal and an inhibitory role attributed to the lower interaction of the thiocarbonyl group with the solvent in the host cavity, respectively.
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| http://dx.doi.org/10.1021/acs.joc.0c02728 | DOI Listing |
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Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Institute of Applied Chemistry, Guizhou University, Guiyang, 550025, China. Electronic address:
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