Category Ranking
98%
Total Visits
921
Avg Visit Duration
2 minutes
Citations
20
Article Abstract
Two novel -Re(CO)-based rectangles {[(CO)Re(μ-Cl)Re(CO)](μ-L)} () and {[(CO)Re(μ-OCH)Re(CO)](μ-L)}() based on new photochromic dithienylethene-containing ligand 2,7-di(pyridin-4-yl)-9,10-bis(5-chloro-2-methylthien-3-yl)-phenanthrene () were prepared. They displayed varying photochromic properties both in solution and in the single-crystal state. Through a judicious choice of the bridging ligands along the short sides of the rectangles, the photophysical and electrochemical properties of the complexes could also be readily tuned.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/acs.inorgchem.0c01845 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Photochromic Rhenium-Based Molecular Rectangles: Syntheses, Structures, Photophysical Properties, and Electrochemistry.
Inorg Chem
October 2020
College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University, Jinan 250014, P. R. China.
Two novel -Re(CO)-based rectangles {[(CO)Re(μ-Cl)Re(CO)](μ-L)} () and {[(CO)Re(μ-OCH)Re(CO)](μ-L)}() based on new photochromic dithienylethene-containing ligand 2,7-di(pyridin-4-yl)-9,10-bis(5-chloro-2-methylthien-3-yl)-phenanthrene () were prepared. They displayed varying photochromic properties both in solution and in the single-crystal state. Through a judicious choice of the bridging ligands along the short sides of the rectangles, the photophysical and electrochemical properties of the complexes could also be readily tuned.
View Article and Find Full Text PDF