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Deformation behavior and precipitation features of an Al-Cu alloy are investigated using uniaxial tensile tests at intermediate temperatures. It is found that the true stress drops with the decreased strain rate or the increased deformation temperature. The number of substructures and the degree of grain elongation decrease with the raised temperature or the decreased strain rate. At high temperatures or low strain rates, some dynamic recrystallized grains can be found. The type of precipitates is influenced by the heating process before hot tensile deformation. The content and size of precipitates increase during tensile deformation at intermediate temperatures. As the temperature increases over 200 °C, the precipitation process (Guinier Preston zone (G.P. zones)→θ'' phase→θ' phase) is enhanced, resulting in increased contents of θ'' and θ' phases. However, θ'' and θ' phases prefer to precipitate along the {020} direction, resulting in an uneven distribution of phases. Considering the flow softening degree and the excessive heterogeneous precipitation of θ'' and θ' phases during hot deformation, the reasonable strain rate and temperature are about 0.0003 s and 150 °C, respectively.
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http://dx.doi.org/10.3390/ma13112495 | DOI Listing |
Phys Chem Chem Phys
September 2025
Department of Chemistry, Malaviya National Institute of Technology Jaipur, Jaipur, 302017, India.
One of the most important puzzles in atmospheric chemistry is the long-lifetime of HO˙ in spite of its low-stabilization energy. In the present work, we have estimated the lifetime of HO˙ using classical dynamics simulations by coupling an available neural-network analytical potential energy surface with a chemical dynamics program. The simulation results clearly indicate that at room temperature, the lifetime of HO˙ can exceed 1 μs under collision-free conditions.
View Article and Find Full Text PDFMol Ecol
September 2025
Faculty of Veterinary Medicine, University of Calgary, Calgary, Alberta, Canada.
Many ant species show dramatic shifts in behaviour when infected with parasites, but the molecular basis of these behavioural changes is not well understood. An example is the wood ant, Formica aserva, which serves as an intermediate host for the lancet liver fluke, Dicrocoelium dendriticum. Infected ants leave their nests during the cool hours of the day, ascend a flower and then attach themselves to a petal with their mandibles.
View Article and Find Full Text PDFEnviron Res
September 2025
School of Environmental Science and Engineering, Huazhong University of Science and Technology, 1037 Luoyu Road, Wuhan, Hubei, 430074, China; Hubei Provincial Engineering Laboratory of Solid Waste Treatment, Disposal and Recycling, 1037 Luoyu Road, Wuhan, Hubei, 430074, China. Electronic address: ho
The activation of peroxymonosulfate (PMS) by biochar has shown promising potential for the efficient degradation and detoxification of antibiotics in wastewater. However, the underlying mechanisms are not fully understood. In this study, Fenton-conditioned sludge-derived biochar (FSBC) was prepared by microwave pyrolysis to activate PMS for the efficient degradation and detoxification of sulfamethoxazole (SMX).
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, Changzhou University, Changzhou 213164, P. R. China.
The development of high-performance, cost-effective non-noble metal catalysts for the oxygen evolution reaction (OER) is critical to advancing sustainable hydrogen production via water electrolysis. Herein, we report a facile and mild strategy for synthesizing amorphous bimetallic organic framework materials (NiFe-MOFs) using pyridine-modified threonine (l-PyThr) as an organic ligand. The optimized NiFe-PyThr-4:1 catalyst exhibits remarkable OER activity, requiring low overpotentials of only 162 and 222 mV to achieve current densities of 10 and 100 mA cm, respectively, along with a small Tafel slope of 34.
View Article and Find Full Text PDFJ Chem Phys
September 2025
Istituto Nazionale di Fisica Nucleare, Sez. Padova, Padova, Italy.
We report here the first measurements of the electron drift mobility μ in gaseous H2 in the intermediate density range 0.5 × 1026 m-3 ≤ N ≤ 5 × 1026 m-3, at low temperature, T = 49.7 K and T = 29.
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