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An advanced understanding of ultrafast coherent electron dynamics is necessary for the application of submicrometre devices under a non-equilibrium drive to quantum technology, including on-demand single-electron sources, electron quantum optics, qubit control, quantum sensing and quantum metrology. Although electron dynamics along an extended channel has been studied extensively, it is hard to capture the electron motion inside submicrometre devices. The frequency of the internal, coherent dynamics is typically higher than 100 GHz, beyond the state-of-the-art experimental bandwidth of less than 10 GHz (refs. ). Although the dynamics can be detected by means of a surface-acoustic-wave quantum dot, this method does not allow for a time-resolved detection. Here we theoretically and experimentally demonstrate how we can observe the internal dynamics in a silicon single-electron source that comprises a dynamic quantum dot in an effective time-resolved fashion with picosecond resolution using a resonant level as a detector. The experimental observations and the simulations with realistic parameters show that a non-adiabatically excited electron wave packet spatially oscillates quantum coherently at ~250 GHz inside the source at 4.2 K. The developed technique may, in future, enable the detection of fast dynamics in cavities, the control of non-adiabatic excitations or a single-electron source that emits engineered wave packets. With such achievements, high-fidelity initialization of flying qubits, high-resolution and high-speed electromagnetic-field sensing and high-accuracy current sources may become possible.
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http://dx.doi.org/10.1038/s41565-019-0563-2 | DOI Listing |
Adv Sci (Weinh)
August 2025
Department of Dermatology, State Key Laboratory of Biotherapy and Cancer Center, West China Hospital, Sichuan University, Chengdu, 610041, P. R. China.
Deuterium labeling is extensively utilized across various scientific disciplines. The dehalogenative deuteration of organic halides offers a promising approach for achieving deuterium labeling. However, existing methods for dehalogenative deuteration primarily focus on sp-hybridized aryl halides, while sp-hybridized alkyl halides, especially bromides and chlorides, exhibit low reactivity and pose significant challenges for reduction.
View Article and Find Full Text PDFChem Sci
August 2025
Shanghai Key Lab of Chemical Assessment and Sustainability, School of Chemical Science and Engineering, Tongji University 1239 Siping Rd. Shanghai 200092 P. R. China
High-voltage p-type organic cathodes are attracting broad attention for boosting zinc batteries, but are hindered by single-electron reactions and low utilization of redox sites due to high reaction energy barriers with incompatible anions. Here we design polyheterocycle organics (PHOs) grafting dual-site-active phenothiazine and piperazine motifs to form donor-acceptor-extended structures which show multi-electron p-type redox reactions for superior anion storage. With the decrease in anionic Stokes radius and the increase in charge density (TFSI → OTF → SO ), SO exhibits the strongest bipedal ion-pairing ability with PHOs during oxidation an ultralow activation energy (0.
View Article and Find Full Text PDFChem Asian J
August 2025
Inorganic & Physical Chemistry Laboratory, CSIR-Central Leather Research Institute, Adyar, Chennai, Tamil Nadu, 600 020, India.
The photophysical and photochemical properties of the organic chromophores are predominantly governed by the aromatic core, electron-donating/withdrawing groups, and inter- and intramolecular electrostatic interactions, while alkyl chains contribute marginally due to their weaker inductive effect. To investigate alkyl chain effects, we synthesized 1-pyrene substituted with N,N-dialkylanilines (C2, C6, C10) via Suzuki coupling. Solvatofluorochromic studies revealed a red-shifted fluorescence with increasing solvent polarity, except in chloroform and methanol, attributed to solute-solvent interaction between solvent proton and the nitrogen atom of N,N-dialkylamine.
View Article and Find Full Text PDFChemSusChem
August 2025
Department of Chemistry "G. Ciamician", Alma Mater Studiorum - University of Bologna, Via P. Gobetti 85, 40129, Bologna, Italy.
A novel and sustainable method is presented for the enantioselective β-alkylation of enals using an electron donor-acceptor (EDA) complex-based strategy. β-Alkyl-γ-azo aldehydes, important intermediates in the synthesis of bioactive compounds, are typically synthesized using organocatalysis, rhodium-catalyzed hydroformylations, or radical additions. Existing photoredox radical approaches-particularly those relying on iminium ion excitation-display severe limitations, particularly related to overall catalytic sustainability.
View Article and Find Full Text PDFJ Am Chem Soc
August 2025
Pingyuan Laboratory, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007, China.
P-chiral tertiary phosphine oxides (TPOs) hold significant synthetic value due to their capacity to serve as versatile precursors for a wide range of valuable P-chiral phosphorus-containing compounds. However, the direct asymmetric oxidation of readily available phosphines into these TPOs remains a substantial challenge, as no efficient and practical methods have been reported to date. In this study, we present the first catalytic asymmetric approach to access P-chiral TPOs through a photoredox-mediated radical process.
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