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Considerable advances in manipulating heat flow in solids have been made through the innovation of artificial thermal structures such as thermal diodes, camouflages, and cloaks. Such thermal devices can be readily constructed only at the macroscale by mechanically assembling different materials with distinct values of thermal conductivity. Here, we extend these concepts to the microscale by demonstrating a monolithic material structure on which nearly arbitrary microscale thermal metamaterial patterns can be written and programmed. It is based on a single, suspended silicon membrane whose thermal conductivity is locally, continuously, and reversibly engineered over a wide range (between 2 and 65 W/m·K) and with fine spatial resolution (10-100 nm) by focused ion irradiation. Our thermal cloak demonstration shows how ion-write microthermotics can be used as a lithography-free platform to create thermal metamaterials that control heat flow at the microscale.
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http://dx.doi.org/10.1021/acs.nanolett.9b00984 | DOI Listing |
Environ Sci Technol
September 2025
School of the Environment, The University of Queensland, Brisbane, Queensland 4072, Australia.
As the global urban heat island (UHI) effect intensifies, understanding how UHI intensity responds to its influencing factors changes is critical for designing effective mitigation strategies. We focused on global megacities, shifted the UHI intensity assessment from physical indicators to human-related parameters, and then evaluated how human-centered UHI intensity responded to influencing factor change. We verified a significant discrepancy between traditional UHI intensity and human-centered UHI intensity worldwide, an average absolute difference of 1.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
The Steve Sanghi College of Engineering, Mechanical Engineering, Northern Arizona University, Flagstaff, Arizona 86011, United States.
This study investigates the HO and CO sorption behavior of two chemically distinct polystyrene-divinylbenzene-based ion exchange sorbents: a primary amine and a permanently charged strong base quaternary ammonium (QA) group with (bi)carbonate counter anions. We compare their distinct interactions with HO and CO through simultaneous thermal gravimetric, calorimetric, gas analysis, and molecular modeling approaches to evaluate their performance for dilute CO separations like direct air capture. Thermal and hybrid (heat + low-temperature hydration) desorption experiments demonstrate that the QA-based sorbent binds both water and CO more strongly than the amine counterparts but undergoes degradation at moderate temperatures, limiting its compatibility with thermal swing regeneration.
View Article and Find Full Text PDFAnal Chem
September 2025
Department of Chemistry, The University of Akron, Akron, Ohio 44325, United States.
Tires are complex polymeric materials composed of rubber elastomers (both natural and synthetic), fillers, steel wire, textiles, and a range of antioxidant and curing systems. These constituents are distributed differently among the various tire parts, which are classified based on their function and proximity to the rim. This study presents a rapid and sensitive approach for the characterization of tire components using mild thermal desorption/pyrolysis (TDPy) coupled to direct analysis in real-time mass spectrometry (DART-MS).
View Article and Find Full Text PDFJ Phys Chem A
September 2025
Department of Basic Science, School of Arts and Sciences, The University of Tokyo, Komaba, Meguro, Tokyo 153-8902, Japan.
Desorption processes of HO molecules from AlO(HO) ( = 3, 5, 7) and AlO(HO)H ( = 4, 6, 8) clusters were investigated using gas-phase thermal desorption spectrometry to evaluate the HO storage capacity and mechanisms of aluminum oxide clusters. The clusters stored approximately 10 HO molecules at ∼300 K, depending on the size (), and released them upon heating. Even after heating to ∼1000 K, 2-4 HO molecules remained bound.
View Article and Find Full Text PDFAnal Chem
September 2025
Laboratory of Organic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zurich, 8093 Zurich, Switzerland.
DNA-encoded libraries have become widely used in drug discovery, and several different setups to link chemical compounds to DNA have been employed in the field, including single-stranded and double-stranded DNA tags as well as a variety of linker chemistries. In our previous study, we observed distinct differences in binding affinities between ligands coupled either to single-stranded or double-stranded DNA; however, the molecular basis for these differences remained unclear. Here, we present a native ion mobility mass spectrometry approach that incorporates gas- and solution-phase activation techniques to systematically investigate these differences, specifically the impact of DNA tags on binding performance in protein-ligand interactions.
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