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Furfural is considered to be an essential biobased platform molecule. Recently, its electrocatalytic hydrogenation is regarded as a more environmentally friendly process compared to traditional catalytic hydrogenation. In this study, a new, continuous-flow approach enabling furfural electrocatalytic reduction was developed. In an undivided multichannel electrochemical flow reactor at ambient temperature and pressure in basic reaction conditions, the yield of furfuryl alcohol reached up to 90% in only 10 min residence time. Interestingly, the faradaic efficiency was 90%, showing a good effectiveness of the consumed electrons in the generation of the targeted compound. Furthermore, the innovation lies in the direct electrolysis using the green solvent ethanol without the need for membrane separation or catalyst modification, which offers further proof for continuous and sustainable production in industry.
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http://dx.doi.org/10.1021/acs.oprd.8b00428 | DOI Listing |
Small
September 2025
School of Photovoltaic and Renewable Energy Engineering, University of New South Wales, Sydney, 2052, Australia.
Plastic waste continues to be a major environmental challenge, worsened by energy-intensive conventional recycling methods that require highly pure feedstocks. In this review, emerging electrochemical upcycling technologies are critically examined, focusing on the electro-oxidation transformation of polyethylene terephthalate (PET) into valuable chemical products. Key reaction pathways and target products are outlined to clarify the selective electrochemical reforming of PET.
View Article and Find Full Text PDFACS Electrochem
September 2025
Department of Chemistry, University of Warwick, Coventry CV4 7AL, United Kingdom.
The surface structure of an electrocatalyst plays a crucial role in determining the activity. As a model system, gold has been widely investigated as an electro-oxidation catalyst, although there has been much less research on the oxygen evolution reaction (OER) in the potential region of gold oxidation. Here, we combine voltammetric scanning electrochemical cell microscopy (SECCM) and electron backscatter diffraction (EBSD), at different spatial and angular resolutions, respectively, to correlate the local crystallographic structure of polycrystalline goldfocusing on grains close to (113), (011), (114), and (111) orientationswith the electrocatalytic behavior for the OER.
View Article and Find Full Text PDFSmall Methods
September 2025
The Research Institute for Advanced Manufacturing, and Department of Mechanical Engineering, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong SAR, 999077, China.
Nitrogen cycle is a fundamental biogeochemical loop existed for millions of years, which involves the transformation of nitrogen-containing chemicals in the environment. However, human activities, especially those since the Industrial Revolution, have significantly disrupted this balance, leading to environmental and energy challenges. Electrocatalysis nitrogen cycle (ENC) offers a promising alternative for the sustainable transformation of nitrogen compounds en route toward rebalancing, with reactions such as the electrocatalytic nitrogen reduction reaction (eNRR) and nitrate/nitrite reduction reaction (eNORR/eNORR) emerging as sustainable alternatives to the traditional Haber-Bosch process.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
Instituto de Cerámica y Vidrio (ICV-CSIC), C/Kelsen 5, 28049 Madrid, Spain.
The oxygen reduction reaction (ORR) is critical to energy conversion technologies and requires efficient catalysts for superior performance. Herein, nitrogen-doped carbide-derived carbon (N-CDC) catalysts are prepared using novel engineered molecular architectures based on polymer-derived ceramic technology. The obtained catalyst materials show a surface N concentration of >5 wt % and a hierarchically porous structure, resulting in a specific surface area of over 2000 m g.
View Article and Find Full Text PDFJ Am Chem Soc
September 2025
Beijing National Laboratory for Molecular Sciences, CAS Laboratory of Colloid and Interface and Thermodynamics, Center for Carbon Neutral Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.
CO electroreduction to produce fuels and chemicals is of great significance. Molecular catalysts offer valuable advantages in light of their well-defined active sites and tunable structural and electronic properties. However, their stability is often compromised by rigid conjugated structures.
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