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Optical Kerr gating technique has been employed to investigate the life history of relativistic electrons in solids by temporally gating their Cherenkov emission. Mega-ampere currents of relativistic electrons are created during ultra-intense (2 × 10 W/cm) laser-solid interactions. In order to measure the lifetime of these relativistic electrons in solids, we temporally gate their Cherenkov emission using an optical Kerr gate (OKG). The OKG is induced in a nonlinear medium, namely, carbon-di-sulphide (CS), with a measured gate-width (FWHM) of 2 ps. The gate femtosecond laser pulse is synchronized with the intense interaction pulse generating relativistic electrons. The arrival time of the gate laser pulse on the CS cell is varied with the help of a delay stage. We find that Cherenkov emission from relativistic electrons created with a ultra-short laser pulse (25 fs) lives as long as 120 ps, a few thousand times that of the incident light pulse.
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http://dx.doi.org/10.1063/1.5054785 | DOI Listing |
Adv Mater
September 2025
Dept. of Physics, Pennsylvania State University, University Park, PA, 16802, USA.
Altermagnets are a newly identified family of collinear antiferromagnets with a momentum-dependent spin-split band structure of non-relativistic origin, derived from spin-group symmetry-protected crystal structures. Among candidate altermagnets, CrSb is attractive for potential applications because of a large spin-splitting near the Fermi level and a high Néel transition temperature of around 700 K. Molecular beam epitaxy is used to synthesize CrSb (0001) thin films with thicknesses ranging from 10 to 100 nm.
View Article and Find Full Text PDFChem Sci
August 2025
Centro de Química Teórica & Computacional (CQT&C), Facultad de Ciencias Exactas, Departamento de Ciencias Químicas, Universidad Andrés Bello Avenida República 275 8370146 Santiago de Chile Chile
Clusters composed of heavy elements, particularly actinides, provide a compelling platform for exploring unconventional bonding and the role of relativistic effects in electronic structure and stability. In this study, we critically reassess the -symmetric PaB cluster, previously claimed to exhibit double Möbius-Craig aromaticity through delocalization of 4σ and 4π electrons. Our potential energy surface (PES) analysis disproves this assignment by showing that the structure is a higher-energy isomer; the most stable form adopts a distorted tetrahedral structure.
View Article and Find Full Text PDFJ Chem Theory Comput
September 2025
Kenneth S. Pitzer Center for Theoretical Chemistry, Department of Chemistry, University of California, Berkeley, California 94720, United States.
Quantum mechanical calculations of core electron binding energies (CEBEs) are relevant to interpreting X-ray photoelectron spectroscopy (XPS). Orbital-optimized density functional theory (OO-DFT) accurately predicts K-edge CEBEs but is challenged by the presence of significant spin-orbit coupling (SOC) at L- and higher edges involving inner-shell orbitals with nonzero angular momentum. To extend OO-DFT to L-edges and higher, our method utilizes scalar-relativistic, spin-restricted open-shell OO-DFT to construct a minimal, quasi-degenerate basis of core-hole states corresponding to a chosen inner-shell (e.
View Article and Find Full Text PDFJ Chem Phys
August 2025
MTA-ELTE "Momentum" Molecular Quantum electro-Dynamics Research Group, Institute of Chemistry, Eötvös Loránd University, Pázmány Péter sétány 1/A, Budapest H-1117, Hungary.
Relativistic, quantum electrodynamics, and non-adiabatic corrections and couplings are computed for the b 3Πg and c3Σg+ electronic states of the helium dimer. The underlying Born-Oppenheimer potential energy curves are converged to 1 ppm (1: 106) relative precision using a variational explicitly correlated Gaussian approach. The quantum nuclear motion is computed over the b 3Πg-c3Σg+ (and B 1Πg-C1Σg+) 9-(12-)dimensional electronic-spin subspace coupled by non-adiabatic and relativistic (magnetic) interactions.
View Article and Find Full Text PDFPhys Chem Chem Phys
September 2025
Faculty of Chemistry, Nicolaus Copernicus University in Toruń, Gagarina Street 7, 87-100 Toruń, Poland.
Recent experimental studies, for example those by Rui Zhang [, 2023, , 084303], have provided a precise new value for the electron affinity of the yttrium atom and fresh insights into its excited states. However, a comprehensive theoretical understanding of its binding and electron affinity remains lacking. Inspired by these findings, we present a detailed theoretical investigation of the excited-state electronic structure of Y.
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