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This study investigates the thermal decomposition behavior of GaN-based epilayers on patterned sapphire substrates (GaN-epi/PSSs) in a quartz furnace tube under a hydrogen atmosphere. The GaN-epi/PSS was decomposed under different hydrogen flow rates at 1200 °C, confirming that the hydrogen flow rate influences the decomposition reaction of the GaN-based epilayer. The GaN was completely removed and the thermal decomposition process yielded gallium oxyhydroxide (GaO₂H) nanostructures. When observed by transmission electron microscopy (TEM), the GaO₂H nanostructures appeared as aggregates of many nanograins sized 2⁻5 nm. The orientation relationship, microstructure, and formation mechanism of the GaO₂H nanostructures were also investigated.
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http://dx.doi.org/10.3390/ma11112082 | DOI Listing |
Int J Phytoremediation
September 2025
Department of Fashion and Textile Design, College of Arts and Design, Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia.
In this paper, lignin was chemically extracted from fibers and modified with branched polyethyleneimine (BPEI) and the resulting samples were applied for the adsorption of two anionic dyes; Acid red 183 (AR183) and Acid blue 25 (AB25) from aqueous suspension. Analytical characterization methods including SEM, FT-IR, TGA/DTG, and XRD were used to analyze the studied samples. The images of the extracted lignin displayed a rough feature.
View Article and Find Full Text PDFFood Res Int
November 2025
Key Laboratory of Food Nutrition and Functional Food of Hainan Province, School of Food Science and Engineering, Hainan University, Haikou 570228, China; Key Laboratory of Tropical Fruits and Vegetables Quality and Safety for State Market Regulation, Hainan Institute for Food Control, Haikou 570314,
Geraniin (GER), a characteristic polyphenol from the pericarp of rambutan, was severely limited in lipid systems due to its poor lipid solubility and thermal stability. In this study, geraniin oleates (GO) with different degrees of esterification were constructed firstly, which significantly enhanced the lipid solubility (104.24-244.
View Article and Find Full Text PDFJ Phys Chem B
September 2025
National Key Laboratory of Solid Rocket Propulsion, Northwestern Polytechnical University, Xi'an 710072, China.
Hexaazaisowurtzitane (CL-20) is a high-energy-density compound with poor thermal stability, which hinders its application in composite energetic systems. A bi-interface structure of polydopamine-coated graphene oxide (GO@PDA) is shown to markedly improve thermal stability compared with pristine CL-20 and single-layer coatings. Reactive molecular dynamics simulations enhanced by a neural network potential (NNP) reveal that the delayed onset of decomposition arises from suppressed NO release and altered spatial density distribution, while interfacial -OH and -COOH groups consume intermediates, redirect decomposition pathways, and inhibit autocatalytic chain reactions.
View Article and Find Full Text PDFInorg Chem
September 2025
Department of Applied Chemistry, Graduate School of Engineering, Osaka Metropolitan University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-853, Japan.
Amorphous molybdenum polysulfides (a-MoS) have attracted considerable attention because of their unique physical and chemical properties, which enable their use in a wide range of applications including energy-storage materials. Among various synthesis methods, thermal decomposition provides an effective route for synthesizing a-MoS. In particular, amorphous molybdenum trisulfide (a-MoS) prepared via thermal decomposition has emerged as a promising active material for energy-storage applications owing to its unique structural and electrochemical characteristics.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2025
Department of Materials Science and Engineering, Norwegian University of Science and Technology, NO-7491 Trondheim, Norway.
LiNiMnO (LNMO) is a promising material for the cathode of lithium-ion batteries (LiBs); however, its high operating voltage causes stability issues when used with carbonate battery electrolytes. Ionic liquids are a viable alternative to conventional carbonate solvents due to their thermal stability and electrochemical window. This work reports the performance of LNMO/Li half cells with an ionic liquid electrolyte (ILE) composed of 0.
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