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Article Abstract

We describe herein the design of a novel molecular scaffold that can induce facile oxidative olefinations when attached to alcohols. Benzylic, homo-, and bishomobenzylic alcohols are utilized. The scaffold can act as a protecting group for the alcohol in other transformations, and it is recoverable in excellent yield. The overall sequence can also be telescoped without purifications of intermediates, representing a net alcohol-based directed -alkenylation.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5966905PMC
http://dx.doi.org/10.1039/c5sc03948gDOI Listing

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