Category Ranking
98%
Total Visits
921
Avg Visit Duration
2 minutes
Citations
20
Article Abstract
A room-temperature, visible-light-driven N-centered iminyl radical-mediated and redox-neutral C-C single bond cleavage/radical addition cascade reaction of oxime esters and unsaturated systems has been accomplished. The strategy tolerates a wide range of O-acyl oximes and unsaturated systems, such as alkenes, silyl enol ethers, alkynes, and isonitrile, enabling highly selective formation of various chemical bonds. This method thus provides an efficient approach to various diversely substituted cyano-containing alkenes, ketones, carbocycles, and heterocycles.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1002/anie.201710618 | DOI Listing |
Publication Analysis
Top Keywords
iminyl radical-mediated
8
c-c single
8
single bond
8
bond cleavage/radical
8
cleavage/radical addition
8
addition cascade
8
oxime esters
8
unsaturated systems
8
visible-light-driven iminyl
4
radical-mediated c-c
4