Highly sensitive and selective detection of Pd ions using a ferrocene-rhodamine conjugate triple channel receptor in aqueous medium and living cells.

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College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Shandong Normal University, Jinan 250014, P. R. China.

Published: January 2018


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Article Abstract

Herein, a novel ferrocene-rhodamine receptor conjugated with an allylimine bridge was facilely synthesized. This triple channel receptor can selectively and sensitively monitor Pd ions through chromogenic, fluorogenic and electrochemical assays in aqueous medium with a low detection limit (8.46 × 10 M) and a fast response (<8 min). It can be applied as a fluorescent probe for effective survey of Pd ions in living cells. Moreover, a plausible recognition mode was proposed and rationalized by theoretical calculations.

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http://dx.doi.org/10.1039/c7an01505dDOI Listing

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