Single Grain Boundary Modeling and Design of Microcrystalline Si Solar Cells.

Materials (Basel)

Department of Opto-Electronic Engineering, National Dong Hwa University, Shoufeng, Hualien 97401, Taiwan.

Published: January 2013


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Article Abstract

For photovoltaic applications, microcrystalline silicon has a lot of advantages, such as the ability to absorb the near-infrared part of the solar spectrum. However, there are many dangling bonds at the grain boundary in microcrystalline Si. These dangling bonds would lead to the recombination of photo-generated carriers and decrease the conversion efficiency. Therefore, we included the grain boundary in the numerical study in order to simulate a microcrystalline Si solar cell accurately, designing new three-terminal microcrystalline Si solar cells. The 3-μm-thick three-terminal cell achieved a conversion efficiency of 10.8%, while the efficiency of a typical two-terminal cell is 9.7%. The three-terminal structure increased the J but decreased the V, and such phenomena are discussed. High-efficiency and low-cost Si-based thin film solar cells can now be designed based on the information provided in this paper.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5452114PMC
http://dx.doi.org/10.3390/ma6010291DOI Listing

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