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Article Abstract
We report the modular synthesis of three different types of neutral κ(2)-P,N-ligands comprising an imine and a phosphine binding site. These ligands were reacted with rhodium, iridium and palladium metal precursors and the structures of the resulting complexes were elucidated by means of X-ray crystallography. We observed that subtle changes of the ligand backbone have a significant influence on the binding geometry und coordination properties of these bidentate P,N-donors.
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| http://dx.doi.org/10.3762/bjoc.12.83 | DOI Listing |
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