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Current policies accelerating photovoltaics (PV) deployments are motivated by environmental goals, including reducing greenhouse gas (GHG) emissions by displacing electricity generated from fossil-fuels. Existing practice assesses environmental benefits on a net life-cycle basis, where displaced GHG emissions offset those generated during PV production. However, this approach does not consider that the environmental costs of GHG release during production are incurred early, while environmental benefits accrue later. Thus, where policy targets suggest meeting GHG reduction goals established by a certain date, rapid PV deployment may have counterintuitive, albeit temporary, undesired consequences. On a cumulative radiative forcing (CRF) basis, the environmental improvements attributable to PV might be realized much later than is currently understood, particularly when PV manufacturing utilizes GHG-intensive energy sources (e.g., coal), but deployment occurs in areas with less GHG-intensive electricity sources (e.g., hydroelectric). This paper details a dynamic CRF model to examine the intertemporal warming impacts of PV deployments in California and Wyoming. CRF payback times are longer than GHG payback times by 6-12 years in California and 6-11 years in Wyoming depending on the PV technology mix and deployment strategy. For the same PV capacity being deployed, early installations yield greater CRF benefits (calculated over 10 and 25 years) than installations occurring later in time. Further, CRF benefits are maximized when PV technologies with the lowest manufacturing GHG footprint (cadmium telluride) are deployed in locations with the most GHG-intensive grids (i.e., Wyoming).
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http://dx.doi.org/10.1021/es502542a | DOI Listing |
Phys Chem Chem Phys
September 2025
Department of Chemistry, Indian Institute of Technology Madras, Chennai, 600036, India.
2-Chlorobutane (2CB) and 2-aminobutane (2AB) are chiral compounds, which play a crucial role in biological complexity. These compounds can be released into the air through natural and man-made processes. Their emission into the atmosphere may influence the air quality and climate significantly.
View Article and Find Full Text PDFPhys Chem Chem Phys
July 2025
Department of Chemistry, University of Helsinki, P.O. Box 55 (A.I. Virtanens plats 1), FIN-00014, Finland.
Peroxy radicals (RO) are ubiquitous intermediates in many oxidation processes, especially in the atmospheric gas phase. The recombination reaction of two peroxy radicals (RO + R'O) has been demonstrated to lead, several steps, to a triplet complex of two alkoxy radicals: (RO˙⋯R'O˙). The different product channels of RO + R'O reactions thus correspond to different reactions of this triplet complex.
View Article and Find Full Text PDFNature
July 2025
Department of Climate and Space Sciences and Engineering, University of Michigan, Ann Arbor, MI, USA.
Climate assessments of civil aviation have consistently quantified the dominant climate-forcing components: (1) CO emissions, (2) NO (NO + NO) emissions and (3) persistent contrails. All three components exert a positive radiative forcing (RF) and lead to climate warming of similar magnitudes. The aviation community is actively seeking to reduce its climate footprint through advanced engine technologies, more sustainable aviation fuel and optimal routing plans.
View Article and Find Full Text PDFJ Phys Chem A
May 2025
Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati, Assam 781039, India.
The CFC alternative, 3,3,3-trifluoro-2(trifluoromethyl)-1-propene, (CF)C═CH (HFIB), plays a pivotal role across various industrial sectors owing to its unique chemical properties, versatility, and diverse applications as a refrigerant, propellant, aerosol, etc. However, its extensive presence in industrial processes raises concerns about its environmental impact. In this study, atmospheric oxidation of HFIB by reaction with Cl, NO, and O is investigated theoretically to unravel the reaction mechanism, thermodynamics, and kinetics.
View Article and Find Full Text PDFEnviron Sci Technol
April 2025
Department of Civil and Environmental Engineering, University of California, Davis, California 95616, United States.
Transforming building materials from net life-cycle COe emitters to carbon sinks is a key pathway towards decarbonizing the industrial sector. Current life-cycle assessments of materials (particularly "low-carbon" materials) often focus on cradle-to-gate emissions, which can exclude emissions and uptake (i.e.
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