Assembly of a 1D coordination polymer through in situ formation of a new ligand by double C-C coupling on CHCl3 under solvothermal conditions.

Inorg Chem

MOE Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China.

Published: September 2009


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Article Abstract

A rare in situ metal/ligand reaction has been observed during the assembly of a manganese-coordination polymer under solvothermal conditions, which leads to double C-C coupling on CHCl(3) involving cleavage of three C-Cl bonds and the formation of two new C-C bonds at the same carbon center.

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http://dx.doi.org/10.1021/ic9011263DOI Listing

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