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A flow injection system with chemiluminescence detection for the determination of asulam, enhancer of the system luminol-H(2)O(2)-horseradish peroxidase, is proposed. The method shows a moderate selectivity against other pesticides usually present in formulations of herbicides and in water. The procedure was applied to the determination of asulam in tap water samples and a recovery study was carried out in order to validate the method. The obtained results show acceptable recovery values (between 88.3 and 93.9%). The detection limit for asulam was 0.12 ng/mL. The precision of the method expressed as relative standard deviation was 1.55% (n = 8), at the 19 ng/mL level.
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http://dx.doi.org/10.1002/bio.1137 | DOI Listing |
Pest Manag Sci
July 2025
Agroscope, Plant Protection Products - Impact and Assessment, Wädenswil, Switzerland.
Background: The herbicide asulam is a weakly adsorbing and, thus, mobile substance. However, due to its rapid degradation, leaching to groundwater is not expected based on simulations with soil leaching models used to predict pesticide concentrations in groundwater as part of the authorization process.
Results: Asulam was, nevertheless, frequently detected in samples from 112 groundwater monitoring sites in Switzerland, albeit at low concentrations up to 0.
Chemosphere
October 2023
Universidad Autónoma de Nuevo León, UANL, Facultad de Ciencias Químicas, Av. Universidad S/N, Cd. Universitaria, C.P. 66455, San Nicolás de Los Garza, Nuevo León, México. Electronic address:
The degradation of asulam herbicide by photo electro-Fenton (PEF) and solar photo electro-Fenton (SPEF) processes was studied using an undivided electrochemical BDD/carbon-felt cell to generate HO continuously. A central composite design combined with response surface methodology was applied to determine the optimal operating conditions of current intensity = 0.30 A, [Fe] = 0.
View Article and Find Full Text PDFHeliyon
June 2023
CQM-UMa, Centro de Química da Madeira, Campus Universitário da Penteada, 9000-390, Funchal, Portugal.
Food contamination with pesticides poses significant risks to consumer safety and undermines confidence in food supply chains. Detecting pesticides in food samples is a challenging task that requires efficient extraction techniques. This study aims to compare and validate two microextraction techniques, μSPEed and μQuEChERS-dSPE, for the simultaneous extraction of eight pesticides (paraquat, thiabendazole, asulam, picloram, ametryn, atrazine, linuron, and cymoxanil) from wastewater samples.
View Article and Find Full Text PDFJ Environ Manage
September 2023
School of Environmental Sciences, University of Liverpool, Liverpool, L69 3GP, UK. Electronic address:
There is a clear need for the development of management strategies to control dominant, perennial weeds and restore semi-natural communities and an important part of this is to know how long control treatments take to be effective and how long they last after treatments stop. Here, we report the results from a 17-year long experiment where we compared the effects of five control treatments on dense Pteridium aquilinum (L. Kuhn) relative to an untreated experimental-control in Derbyshire, UK.
View Article and Find Full Text PDFEnviron Res
August 2021
Department for Health Evidence, Radboud Institute for Health Sciences, Radboud University Medical Center, Nijmegen, the Netherlands. Electronic address:
Background: Residential exposure to pesticides may occur via inhalation of airborne pesticides, direct skin contacts with pesticide-contaminated surfaces, and consumption of food containing pesticide residues. The aim was to study the association of dermal exposure to pesticides between the use and non-use periods, between farmer and non-farmer families and between dermal exposure and the excretion of metabolites from urine in residents living close to treated agricultural fields.
Methods: In total, 112 hand wipes and 206 spot urine samples were collected from 16 farmer and 38 non-farmer participants living within 50 m from an agricultural field in the Netherlands.