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The transmission of direct, diffuse and global solar radiation in and around canopy gaps occurring in an uneven-aged, evergreen Nothofagus betuloides forest during the growing season (October 2006-March 2007) was estimated by means of hemispherical photographs. The transmission of solar radiation into the forest was affected not only by a high level of horizontal and vertical heterogeneity of the forest canopy, but also by low angles of the sun's path. The below-canopy direct solar radiation appeared to be variable in space and time. On average, the highest amount of transmitted direct solar radiation was estimated below the undisturbed canopy at the southeast of the gap centre. The transmitted diffuse and global solar radiation above the forest floor exhibited lower variability and, on average, both were higher at the centre of the canopy gaps. Canopy structure and stand parameters were also measured to explain the variation in the below-canopy solar radiation in the forest. The model that best fit the transmitted below-canopy direct solar radiation was a growth model, using plant area index with an ellipsoidal angle distribution as the independent variable (R (2) = 0.263). Both diffuse and global solar radiation were very sensitive to canopy openness, and for both cases a quadratic model provided the best fit for these data (R (2) = 0.963 and 0.833, respectively). As much as 75% and 73% of the variation in the diffuse and global solar radiation, respectively, were explained by a combination of stand parameters, namely basal area, crown projection, crown volume, stem volume, and average equivalent crown radius.
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http://dx.doi.org/10.1007/s00484-009-0222-7 | DOI Listing |
Adv Mater
September 2025
School of Architecture, Southeast University, Nanjing, 210096, China.
Buildings are increasingly being conceived as dynamic systems that interact with their surroundings to optimize energy performance and enhance occupant comfort. This evolution in architectural thinking draws inspiration from biological systems, where the building envelope functions like a thermally responsive "skin" that can autonomously adjust its optical and thermal properties in response to environmental temperature changes. Among the many approaches developed for smart building envelopes, passive thermoresponsive spectral modulation systems have attracted growing interest due to their structural simplicity and low energy demand.
View Article and Find Full Text PDFAdv Mater
September 2025
Guangdong Provincial Key Laboratory of Optical Information Materials and Technology & Institute of Electronic Paper Displays, South China Academy of Advanced Optoelectronics, South China Normal University, Guangzhou, 510006, P. R. China.
Establishing a low-resistance perovskite/ITO contact using self-assembled molecules (SAMs) is crucial for efficient hole transport in perovskite solar cells (PSCs) without a pre-deposited hole-transporting layer. However, SAMs at the buried interface often encounter issues like nonuniform distribution and molecular aggregation during the extrusion process, leading to significant energy loss. Herein, a molecular hybrid bridging strategy by incorporating a novel small molecule is proposed, (2-aminothiazole-4-yl)acetic acid (ATAA), featuring a thiazole ring and carboxylic acid group, along with the commonly used SAM, 4-(2,7-dibromo-9,9-dimethylacridin-10(9H)-yl)butyl)phosphonic acid (DMAcPA), into the perovskite precursor to synergistically optimize the buried interface.
View Article and Find Full Text PDFNanoscale Adv
August 2025
Department of Metallurgical and Materials Engineering, Faculty of Engineering, University of Dokuz Eylül İzmir Turkey.
Thin films of CuSn Gd S were prepared on soda-lime glass substrates using spin coating in a sulfur-rich environment. We investigated how doping CuSnS with gadolinium (Gd) affected its structural, morphological, and optical properties using X-ray diffraction (XRD), Raman spectroscopy, field emission scanning electron microscopy (FE-SEM), and UV-Vis spectroscopy. XRD showed that all samples had a polycrystalline monoclinic structure, while FE-SEM revealed a mix of spherical and polygon-shaped grains.
View Article and Find Full Text PDFActa Crystallogr E Crystallogr Commun
September 2025
Laboratory of Matter Environmental and Solar Energy Sciences Research Team: Crystallography and Molecular Physics Félix Houphouët-Boigny University, Abidjan,Ivory Coast.
The structure of the title compound, CHClN, was determined at low temperature (100 K). In the crystal, the mol-ecules are connected through C-H⋯N and C-H⋯Cl inter-molecular hydrogen bonds generating a network that extend along the [010] direction. In addition, C-H⋯π and π-π stacking inter-actions as well as inter-molecular contacts contribute to the cohesion of the structure.
View Article and Find Full Text PDFAtomic layer deposition (ALD) enables an excellent surface coverage and uniformity in the preparation of large-area metal-oxide thin films. In particular, ALD-processed SnO has demonstrated great potential as an electron transport layer in flexible perovskite solar cells (PSCs) and tandem modules. However, the poor electrical conductivities and surface wettabilities of amorphous SnO remain critical challenges for commercialization.
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