Background: According to the GLOBCAN2022 database, pancreatic cancer has become the 6th leading cause of cancer-related death worldwide. The latest statistics suggest that the incidence of pancreatic cancer is increasing at a rate of 0.5% to 1.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
March 2023
The level of hydrogen sulfide (HS) in human body is related to many diseases, such as Alzheimer's disease, Down syndrome, etc. Therefore, the detection of HS level in biological systems is very important and has attracted great attention from scientific and clinical researchers. Understanding the design and working mechanism of fluorescent probes for HS level detection is important for building new highly efficient fluorescent probe.
View Article and Find Full Text PDFJ Mol Model
June 2022
CH@C was the first example within which an organic molecule has been embedded in C. CH can rotate freely in the molecular cage, and the carbon skeleton structure of the C has no obvious deformation. The electronic structure of CH@C and interaction between C and CH were studied under quantum mechanical calculation method.
View Article and Find Full Text PDFUnderstanding the nature of glass transition is still a great challenge. Glass transition is widely observed in many glassy materials; however, it has never been unambiguously observed in reversible cross-linked polymer, which is an ideal model of the percolation process. Herein, we report the synthesis of a reversible cross-linked polymer incorporated with four-armed Diels-Alder (DA) dynamic covalent bonds, and the robust experimental observation of percolation-induced glass transition in this reversible four-armed cross-linked polymer (DAMF1).
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