The present work is devoted to the biological effects of sol-gel-derived silica (Si)-copper (Cu) nanomaterials. Tetraethyl orthosilane (TEOS) was used as a silica precursor; copper was introduced as a solution in ethanol with Cu(OH). The obtained samples were denoted as Si/Cu (gel) and Si/Cu/500 (500 °C heat-treated).
View Article and Find Full Text PDFSilica-poly (vinylpyrrolidone) hybrid material was prepared using the sol-gel method. Tetramethyl ortosilane (TMOS) was used as a silica precursor. XRD analysis established that the as-prepared material is amorphous.
View Article and Find Full Text PDFThe present work deals with the sol-gel synthesis of silica-poly (vinylpyrrolidone) hybrid materials. The nanohybrids (Si-PVP) have been prepared using an acidic catalyst at ambient temperature. Tetramethyl ortosilane (TMOS) was used as a silica precursor.
View Article and Find Full Text PDFThe effect of copper as a minority alloying element on the corrosion behaviour of amorphous and crystalline AlNiSi and AlNiSiCu alloys was investigated in this study. Amorphous alloys were produced as rapidly solidified ribbons using the Chill Block Melt Spinning (CBMS) method and subsequently annealed to complete crystallisation. The corrosion rate of alloys was obtained through continuous immersion tests in 3.
View Article and Find Full Text PDFWaste Manag Res
February 2011
The purpose of this study was to investigate the possibility of separating pyrometallurgical copper (fayalite) slag by oxidation in a synthetic air atmosphere into ferrous and silicate phases suitable for resources to be recovered from them. Isothermal oxidation kinetics and the most probable reaction models are studied in the temperature range of 773 to 1173 K using thermogravimetric analysis data and the classical Johnson-Mehl-Avrami-Yerofeev-Kolmogorov (JMAYK) equation. Depending on the model applied, the activation energies of fayalite slag oxidation in the temperature range of 773-973 K were: D1: 37.
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