Active-matter systems are inherently out-of-equilibrium and perform mechanical work by utilizing their internal energy sources. Breakdown of time-reversal symmetry (BTRS) is a hallmark of such dissipative nonequilibrium dynamics. We introduce a robust, experimentally accessible, noninvasive, quantitative measure of BTRS in terms of the Kullback-Leibler divergence in collision events, demonstrated in our novel artificial active matter, comprised of battery-powered spherical rolling robots whose energetics in different modes of motion can be measured with high precision.
View Article and Find Full Text PDFIn a vertically shaken vertical round container of loosely packed nominally-vertical toothpicks, the toothpicks gradually progress horizontally. This vibration-driven locomotion is also observed in vintage toy football players on a buzzing support and in modern "Bristlebots" which are toothbrush heads with phone buzzers mounted on top. In all these cases the objects, or their lower parts, have a slant.
View Article and Find Full Text PDFTire and brake-wear emissions, in particular nanoparticulate aerosols, can potentially impact human health and the environment adversely. While there is considerable phenomenological data on tire wear, the creation and environmental persistence of particulate pollutants is not well understood. Here, we unequivocally show that normal mechanical tire wear results in two distinct micro and nanoplastic (MNP) populations: a smaller, aerosolized fraction (<10 μm), and larger microplastics.
View Article and Find Full Text PDFWe present emergent behaviour of storing mechanical deformation in compressed soft cellular materials (a network of soft polymeric rods). Under an applied compressive strain field, the soft cellular material transits from an elastic regime to a 'pseudo-plastic' regime (not to be confused with pseudoplasticity in fluids). In the elastic phase, it is capable of forgetting (or relaxing) any applied indentation once the applied indentation is removed.
View Article and Find Full Text PDFThe usual basis to analyze heat transfer within materials is the equation formulated 200 years ago, Fourier's law, which is identical mathematically to the mass diffusion equation, Fick's law. Revisiting this assumption regarding heat transport within translucent materials, performing the experiments in vacuum to avoid air convection, we compare the model predictions to infrared-based measurements with nearly mK temperature resolution. After heat pulses, we find macroscale non-Gaussian tails in the surface temperature profile.
View Article and Find Full Text PDFBreast cancer is considered to be happened due to genetic aberration. Out of several genes expressed, it is found that cadherin 1, type 1 (CDH1) is responsible in several ways to control the metabolic order in human. Deregulation of the function of protein E-cadherin, expressed from CDH1 plays an important role in lobular breast cancer.
View Article and Find Full Text PDFJ Biomol Struct Dyn
June 2024
As 20 naturally occurring amino acids are coded by 61 mRNA codons out of 64, it is obvious that 61→20 cannot have one-to-one mapping which generates the problem of codon degeneracy. Despite several efforts there is no specific outcome which can describe this well-known enigmatic degeneracy of the codon table. Since, every biological behaviour is regulated by protein which in turn consists of amino acids bearing the inherent characteristics of degeneracy among mRNA codons (Crick F.
View Article and Find Full Text PDFUnder the influence of oscillatory shear, a monolayer of frictional granular disks exhibits two dynamical phase transitions: a transition from an initially disordered state to an ordered crystalline state and a dynamic active-absorbing phase transition. Although there is no reason a priori for these to be at the same critical point, they are. The transitions may also be characterized by the disk trajectories, which are nontrivial loops breaking time-reversal invariance.
View Article and Find Full Text PDFThe dynamics of n rigid objects, each having d degrees of freedom, is played out in the configuration space of dimension nd. Being rigid, there are additional constraints at work that renders a portion of the configuration space inaccessible. In this paper, we make the assertion that treating the overall dynamics as a Markov process whose states are defined by the number of contacts made between the rigid objects provides an effective coarse-grained characterization of the otherwise complex phenomenon.
View Article and Find Full Text PDFRev Sci Instrum
December 2021
We present a method for modifying a continuous flow cryostat and a steel plate DAC (Diamond Anvil Cell) to perform high pressure micro-Raman experiments at low temperatures. Despite using a steel DAC with a lower specific heat capacity (∼335 J/kg K), this setup can routinely perform high pressure (∼10 GPa) measurements at temperatures as low as 26 K. This adaptation is appropriate for varying the temperature of the sample while keeping it at a constant pressure.
View Article and Find Full Text PDFWe investigate experimentally the dynamic phase transition from compressed to buckled phases for thin sheets of rubber. We find that the rubber strips enter a highly compressed, metastable state when compression speed is high. During the compressed phase, higher modes grow, followed by mode coarsening.
View Article and Find Full Text PDFIn this paper, we study the structure of the solid selenium (Se) formed by the vapor deposition method. We provide direct visual evidence that faceted crystal-like shapes obtained from vapor phase deposition are a self-assembly of linear strands that have a persistence length of 10m. These strands are held together by weak forces and can easily be separated.
View Article and Find Full Text PDFAmong all the proteins of Periplasmic C type Cytochrome family obtained from cytochrome found in , only the Periplasmic C type Cytochrome A (PPCA) protein can recognize the deoxycholate (DXCA), while its other paralogs do not, as observed from the crystal structures. Though some existing works have used graph-theoretic approaches to realize the 3-D structural properties of proteins, its usage in the rationalisation of the physiochemical behavior of proteins has been very limited. To understand the driving force towards the recognition of DXCA exclusively by PPCA among its paralogs, in this work, we propose two graph theoretic models based on the combinatorial properties, namely, and , of the nucleotide bases and the amino acid residues, respectively.
View Article and Find Full Text PDFN95 respirators comprise a critical part of the personal protective equipment used by frontline health-care workers and are typically meant for one-time usage. However, the recent COVID-19 pandemic has resulted in a serious shortage of these masks leading to a worldwide effort to develop decontamination and re-use procedures. A major factor contributing to the filtration efficiency of N95 masks is the presence of an intermediate layer of charged polypropylene electret fibers that trap particles through electrostatic or electrophoretic effects.
View Article and Find Full Text PDFIt is of interest to fabricate curved surfaces in three dimensions from homogeneous material in the form of flat sheets. The aim is not just to obtain a surface which has a desired intrinsic Riemannian metric, but to get the desired embedding in up to translations and rotations. In this paper, we demonstrate three generic methods of moulding a flat sheet of thermo-responsive plastic by selective contraction induced by targeted heating.
View Article and Find Full Text PDFKeeping current interests to identify materials with intrinsic magnetodielectric behaviour near room temperature and with novel pyroelectric current anomalies, we report temperature and magnetic-field dependent behavior of complex dielectric permittivity and pyroelectric current for an oxide, LiNiMoO, containing magnetic ions with (distorted) honey-comb and chain arrangement and ordering magnetically below 8 K. The dielectric data reveal the existence of relaxor ferroelectricity behaviour in the range 160-240 K and there are corresponding Raman mode anomalies as well in this temperature range. Pyrocurrent behavior is also consistent with this interpretation, with the pyrocurrent peak-temperature interestingly correlating with the poling temperature.
View Article and Find Full Text PDFIn this note we introduce a hierarchy of phase spaces for static friction, which give a graphical way to systematically quantify the directional dependence in static friction via subregions of the phase spaces. We experimentally plot these subregions to obtain phenomenological descriptions for static friction in various examples where the macroscopic shape of the object affects the frictional response. The phase spaces have the universal property that for any experiment in which a given object is put on a substrate fashioned from a chosen material with a specified nature of contact, the frictional behaviour can be read off from a uniquely determined classifying map on the control space of the experiment which takes values in the appropriate phase space.
View Article and Find Full Text PDFMagic sand, a hydrophobic toy granular material, is widely used in popular science instructions because of its nonintuitive mechanical properties. A detailed study of the failure of an underwater column of magic sand shows that these properties can be traced to a single phenomenon: the system self-generates a cohesive skin that encapsulates the material inside. The skin, consisting of pinned air-water-grain interfaces, shows multiscale mechanical properties: they range from contact-line dynamics in the intragrain roughness scale, to plastic flow at the grain scale, all the way to sample-scale mechanical responses.
View Article and Find Full Text PDFSoft Matter
February 2016
Efficient mixing strategies in a fluid involve generation of multi-scale flows which are strongly suppressed in highly viscous systems. In this work, we report a novel form of multi-scale flow, driven by an external electric field, in a highly viscous (η∼ 1 Pa s) oil-in-oil emulsion system consisting of micron-size droplets. This electro-hydrodynamic flow leads to dynamical organization at spatial scales much larger than that of the individual droplets.
View Article and Find Full Text PDFJ Phys Condens Matter
October 2015
Arguments based on the Mermin-Wagner theorem suggest that the quasi-1D trigonal phase of Se should be unstable against long wavelength perturbations. Consisting of parallel Se-Se chains, this essentially fragile solid undergoes a partial transition to a monoclinic structure (consisting of 8-membered rings) at low temperatures (≈50 K), and to a distorted trigonal phase at moderate pressures (≈3GPa). Experimental investigations on sub-millimeter-sized single crystals provide clear evidence that these transitions occur via a novel and counter-intuitive route.
View Article and Find Full Text PDFA monolayer of granular spheres in a cylindrical vial, driven continuously by an orbital shaker and subjected to a symmetric confining centrifugal potential, self-organizes to form a distinctively asymmetric structure which occupies only the rear half-space. It is marked by a sharp leading edge at the potential minimum and a curved rear. The area of the structure obeys a power-law scaling with the number of spheres.
View Article and Find Full Text PDFObservation of ferroelectricity among non-d(0) systems, which was believed for a long time an unrealistic concept, led to various proposals for the mechanisms to explain the same (i.e. magnetically induced ferroelectricity) during last decade.
View Article and Find Full Text PDFWe report on the spreading of triboelectrically charged glass particles on an oppositely charged surface of a plastic cylindrical container in the presence of a constant mechanical agitation. The particles spread via sticking, as a monolayer on the cylinder's surface. Continued agitation initiates a sequence of instabilities of this monolayer, which first forms periodic wavy-stripe-shaped transverse density modulation in the monolayer and then ejects narrow and long particle-jets from the tips of these stripes.
View Article and Find Full Text PDFLab Chip
April 2014
We demonstrate a simple and robust method to produce large 2-dimensional and quasi-3-dimensional arrays of tunable liquid microlenses using a time varying external electric field as the only control parameter. With increasing frequency, the shape of the individual lensing elements (~40 μm in diameter) evolves from an oblate (lentil shaped) to a prolate (egg shaped) spheroid, thereby making the focal length a tunable quantity. Moreover, such microlenses can be spatially localized in desired configurations by patterning the electrode.
View Article and Find Full Text PDFThe quasi-one-dimensional, chiral crystal structure of Selenium has fascinating implications: we report simultaneous magnetic and ferroelectric order in single crystalline Se microtubes below ≈40 K. This is accompanied by a structural transition involving a partial fragmentation of the infinite chains without losing overall crystalline order. Raman spectral data indicate a coupling of magnons with phonons and electric field, while the dielectric constant shows a strong dependence on magnetic field.
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