Impact of high energy photons on physical, structural and magnetic properties of MnZnFeNdO nanoparticles.

Ultrafine powders of Nd doped Mn-Zn ferrite powders with composition MnZnFeNdO (x = 0.04, 0.06, 0.

The translating bacterial ribosome at 1.55 Å resolution generated by cryo-EM imaging services.

Our understanding of protein synthesis has been conceptualised around the structure and function of the bacterial ribosome. This complex macromolecular machine is the target of important antimicrobial drugs, an integral line of defence against infectious diseases. Here, we describe how open access to cryo-electron microscopy facilities combined with bespoke user support enabled structural determination of the translating ribosome from Escherichia coli at 1.

Apple Leave Disease Detection Using Collaborative ML/DL and Artificial Intelligence Methods: Scientometric Analysis.

Infection in apple leaves is typically brought on by unanticipated weather conditions such as rain, hailstorms, draughts, and fog. As a direct consequence of this, the farmers suffer a significant loss of productivity. It is essential to be able to identify apple leaf diseases in advance in order to prevent the occurrence of this disease and minimise losses to productivity caused by it.

From Recoding to Peptides for MHC Class I Immune Display: Enriching Viral Expression, Virus Vulnerability and Virus Evasion.

Many viruses, especially RNA viruses, utilize programmed ribosomal frameshifting and/or stop codon readthrough in their expression, and in the decoding of a few a UGA is dynamically redefined to specify selenocysteine. This recoding can effectively increase viral coding capacity and generate a set ratio of products with the same N-terminal domain(s) but different C-terminal domains. Recoding can also be regulatory or generate a product with the non-universal 21st directly encoded amino acid.

Structural basis of ribosomal frameshifting during translation of the SARS-CoV-2 RNA genome.

Programmed ribosomal frameshifting is a key event during translation of the severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) RNA genome that allows synthesis of the viral RNA-dependent RNA polymerase and downstream proteins. Here, we present the cryo-electron microscopy structure of a translating mammalian ribosome primed for frameshifting on the viral RNA. The viral RNA adopts a pseudoknot structure that lodges at the entry to the ribosomal messenger RNA (mRNA) channel to generate tension in the mRNA and promote frameshifting, whereas the nascent viral polyprotein forms distinct interactions with the ribosomal tunnel.

Magnetic Exchange Interaction in Nitronyl Nitroxide Radical-Based Single Crystals of 3d Metal Complexes: A Combined Experimental and Theoretical Study.

Two stable nitronyl nitroxide free radicals { = 4'-methoxy-phenyl-4,4,5,5,-tetramethylimidazoline-1-oxyl-3-oxide (NNPhOMe) and = 2-(2'-thienyl)-4,4,5,5-tetramethylimidazoline 3-oxide 1-oxyl (NNT)} are successfully synthesized using Ullmann condensation. The reactions of these two radicals with 3d transition metal ions, in the form of M(hfac) (where M = Co or Mn, hfac: hexafluoroacetylacetone), result in four metal-organic complexes Co(hfac)(NNPhOMe), ; Co(hfac)(NNT)·(HO), ; Mn(hfac)(NNPhOMe)·(CH), ; and Mn(hfac)(NNT), . The crystal structure and magnetic properties of these complexes are investigated by single-crystal X-ray diffraction, dc magnetization, infrared, and electron paramagnetic resonance spectroscopies.

Biopolymer assisted synthesis of silica-carbon composite by spray drying.

Spray drying had been used to synthesize silica-carbon black nanocomposite micrometric granules with a uniform distribution of the two components. This was achieved by hindering the preferential diffusion of hydrophobic carbon and hydrophilic silica particles in the water droplets during evaporative assembly by introducing gum arabic as a stabilizing agent and network former. Both positive and negatively charged silica nanoparticles were used to check the stability of the sol and its effect on the morphology of the spray dried granules.

Ribosomal frameshifting and transcriptional slippage: From genetic steganography and cryptography to adventitious use.

Genetic decoding is not 'frozen' as was earlier thought, but dynamic. One facet of this is frameshifting that often results in synthesis of a C-terminal region encoded by a new frame. Ribosomal frameshifting is utilized for the synthesis of additional products, for regulatory purposes and for translational 'correction' of problem or 'savior' indels.

Synthesis and spectral studies of metal complexes of a Schiff base derived from (2-amino-5-chlorophenyl)phenyl methanone.

Some new complexes of Mn(II), Co(II), Ni(II), Cu(II), Zn(II), and Fe(III) with the Schiff base 5-chloro-2-(furan-2-yl methylamino)phenyl)phenyl methanone has been synthesized and characterized by elemental analysis, spectroscopic data including FT-IR, (1)H NMR, Electronic, ESI mass, Mössbauer & ESR. It has been found that the Schiff base behaves as a neutral bidentate N, O donor which chelates with the metal ions in 1:2 stoichiometry. Magnetic moment and electrolytic conductance data confirms this.

Enhanced thermoelectric properties of selenium-deficient layered TiSe(2-x): a charge-density-wave material.

In the present work, we report on the investigation of low-temperature (300-5 K) thermoelectric properties of hot-pressed TiSe2, a charge-density-wave (CDW) material. We demonstrate that, with increasing hot-pressing temperature, the density of TiSe2 increases and becomes nonstoichiometric owing to the loss of selenium. X-ray diffraction, scanning electron microscopy, and transimission electron microscopy results show that the material consists of a layered microstructure with several defects.

Core-shell Prussian blue analogue molecular magnet Mn(1.5)[Cr(CN)6]·mH2O@Ni(1.5)[Cr(CN)6]·nH2O for hydrogen storage.

Core-shell Prussian blue analogue molecular magnet Mn1.5[Cr(CN)6]·mH2O@Ni1.5[Cr(CN)6]·nH2O has been synthesized using a core of Mn1.

Thermoelectric performance of layered SrxTiSe2 above 300 K.

In this paper we report the thermoelectric performance of Sr intercalated TiSe(2) above 300 K. Refined x-ray diffraction, high resolution transmission electron microscopy and scanning electron microscopy images show well oriented polycrystalline grains along a (0 0 l) direction and layered growth of the sample. Intercalation of Sr in TiSe(2) shows an improved Seebeck coefficient (α) value without altering the polarity of the majority charge carrier.

Investigation of Ti layer thickness dependent structural, magnetic, and photoemission study of nanometer range Ti/Ni multilayer structures.

Structural, magnetic, and electronic properties of Ti/Ni multilayer (ML) samples as a function of Ti layer thickness are studied and reported in this paper. For this purpose [Ti (t nm)/Ni (5 nm)] x 10 ML samples, where t = 3, 5, and 7 nm have been deposited by using electron beam evaporation technique under UHV conditions at room temperature. Structure of ML samples were determined by using XRD (X-ray diffraction) technique and observed that Titanium is deposited mainly in amorphous nature with FCC structure at lower Ti layer thickness of 3 nm, which transform to crystalline HCP structures above than this Ti layer thickness.