Sight into a Rare-Earth-Based Catalyst with Spatial Confinement Effect from the Perspective of Electronic Structure.

Rare-earth elements include 15 kinds of lanthanides as well as Sc and Y elements. Interestingly, the special electronic configuration of a lanthanide rare earth is [Xe]4f5d6s ( = 0-14), which results in rare-earth materials' unique activity in such areas as thermal catalysis, electrocatalysis, photocatalysis, etc. It is worth noting that a class of materials with spatial confinement effects are playing an increasingly important role in the catalytic performance; especially, the construction of hollow multishelled structures (HoMSs) can further enhance the activity of rare-earth catalytic materials.

Large-Scale Fabrication of Nanostructure on Bio-Metallic Substrate for Surface Enhanced Raman and Fluorescence Scattering.

The integration of surface-enhanced Raman scattering (SERS) and surface-enhanced fluorescence (SEF) has attracted increasing interest and is highly probable to improve the sensitivity and reproducibility of spectroscopic investigations in biomedical fields. In this work, dual-mode SERS and SEF hierarchical structures have been developed on a single bio-metallic substrate. The hierarchical structure was composed of micro-grooves, nano-particles, and nano-ripples.

Laser-Induced Graphene on Additive Manufacturing Parts.

Additive manufacturing (AM) has become more prominent in leading industries. Recently, there have been intense efforts to achieve a fully functional 3D structural electronic device by integrating conductive structures into AM parts. Here, we introduce a simple approach to creating a conductive layer on a polymer AM part by CO₂ laser processing.

Femtosecond Laser Produced Hydrophobic Hierarchical Structures on Additive Manufacturing Parts.

With the recent expansion of additive manufacturing (AM) in industries, there is an intense need to improve the surface quality of AM parts. A functional surface with extreme wettability would explore the application of AM in medical implants and microfluid. In this research, we propose to superimpose the femtosecond (fs) laser induced period surface structures (LIPSS) in the nanoscale onto AM part surfaces with the micro structures that are fabricated in the AM process.

Simulation of fluorescence enhancement by an AFM tip on a gold particle quenched emitter.

The local field enhancement in proximity of metallic nanostructures can strongly modify the excitation and emission behaviors for the nearby fluorophore. In this paper, Maxwell's time-dependent curl equations are solved by the finite-difference time-domain method to investigate the electric field enhancement around an atomic-force microscopy (AFM) tip and a Au nanosphere (NS). To lower the background fluorescence signal, we proposed to induce the fluorescence quenching by placing the emitter at an optimized position that is 2 nm away from the Au NS.

Super-focusing of center-covered engineered microsphere.

Engineered microsphere possesses the advantage of strong light manipulation at sub-wavelength scale and emerges as a promising candidate to shrink the focal spot size. Here we demonstrated a center-covered engineered microsphere which can adjust the transverse component of the incident beam and achieve a sharp photonic nanojet. Modification of the beam width and working distance of the photonic nanojet were achieved by tuning the cover ratio of the engineered microsphere, leading to a sharp spot size which exceeded the optical diffraction limit.