Publications by authors named "Le Van Hai"

This study explores the potential application of lignin nanoparticles and chitosan-lignin nanoparticles (CLNs) as hydrophobic barrier coatings for paperboard. The lignin nanoparticles were initially prepared using a mixed solvent of ethanol and acetone. Their characteristics were examined via scanning electron microscopy (SEM) and dynamic light scattering, which revealed particle sizes in the range of 180-400 nm.

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Wood cellulose is an abundant bio-based resource with diverse applications in construction, cosmetics, packaging, and the pulp and paper industries. Transparent wood (TW) is a novel, high-quality wood material with several advantages over traditional transparent materials (e.g.

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This study reports dicarboxylate cellulose nanofibrils (DCNF) as a novel reducing and supporting agent for producing silver nanoparticles (AgNPs) with high efficiency (63.82 % reduction) and loading (6.88 %) using UV light.

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In this study, lignin nanoparticles (LN) and octadecylamine-modified LN (LN-ODA) were utilized as coating materials to enhance the hydrophobic, antioxidant, and ultraviolet radiation-shielding (UV-shielding) properties of a TEMPO-oxidized nanocellulose film (TOCNF). The water contact angle (WCA) of the TOCNF was approximately 53° and remained stable for 1 min, while the modified LN-ODA-coated TOCNF reached over 130° and maintained approximately 85° for an hour. Pure TOCNF exhibited low antioxidant properties (4.

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Objectives: This study aims to investigate the effect of coating time on the formation of hydroxyapatite (HA) coating layer on ZK60 substrate and understand the biodegradation behavior of the coated alloy for biodegradable implant applications.

Methods: Biodegradable ZK60 alloy was coated by HA layer for different times of 0.5, 1, 2, and 4 h by chemical conversion method.

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This paper reports on multiple stage bleaching and its effect on the mechanical and swelling properties of compressed wood (CW). The natural wood specimen was bleached with NaClO in five steps and three hot-pressing conditions. Their effects were investigated in morphologies: lignin content, alpha-cellulose content, compression ratio, mechanical properties, swelling and, water contact angle.

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Transparent-wood (TW) is an emerging research topic that can be applied to biobased products. However, it is necessary to fill pores in TW with natural substances to prepare all-biobased TW. This paper reports an all-biobased TW by infiltrating cellulose nanofiber (CNF) and chitosan (CTS) suspensions into the bleached wood.

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Objectives: The aim of this study is to evaluate the effect of pH treatment on the formation of hydroxyapatite (HA) coating layer and the biodegradation rate of hydroxyapatite coated AZ31 alloy for applications in biodegradable implants.

Methods: HA was grown on the surface of AZ31 substrate at three different pH solutions of 7.5, 9.

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This paper reports that, by simply blending two heterogeneous polysaccharide nanofibers, namely chitosan nanofiber (ChNF) and cellulose nanofiber (CNF), a ChNF-CNF composite was prepared, which exhibited improved mechanical properties and antioxidant activity. ChNF was isolated using the aqueous counter collision (ACC) method, while CNF was isolated using the combination of TEMPO oxidation and the ACC method, which resulted in smaller size of CNF than that of ChNF. The prepared composite was characterized in terms of morphologies, FT-IR, UV visible, thermal stability, mechanical properties, hygroscopic behaviors, and antioxidant activity.

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This paper reports the preparation, characterization and properties of synthetic melanin-like nanoparticle (MNP) reinforced chitosan nanocomposite films. The MNP was prepared using dopamine hydrochloride and sodium hydroxide which followed by spontaneous oxidation. The prepared MNP was spherical in shape and in the size range of ∼100 nm.

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Article Synopsis
  • This paper presents a green nanocomposite created by blending chitin and bamboo cellulose nanofibers without using chemicals to dissolve them.
  • The resulting nanocomposite shows enhanced mechanical properties, with tensile strength increasing up to 3 times as bamboo cellulose concentration rises, while also maintaining good thermal stability and complete biodegradability within a week.
  • The promising properties make this nanocomposite a potential candidate for sustainable food packaging applications.
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While the demand for lightweight high-strength nanocomposites is immense, their progress has been severely limited due to inferior filler dispersion and filler-matrix interface adhesion. This article reports a novel modification of graphene oxide (GO) encapsulated by the copolymer of polydopamine (PD) and polyethylenimine (PEI) a Michael addition reaction, aiming to create robust ethylene vinyl acetate copolymer (EVA) nanocomposites even at very low amounts of filler loading by overcoming the above hindrances. It has been found that the addition of only 1.

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In this research, cellulose nanofiber (CNF) was isolated by the combination of chemical 2,2,6,6-tetramethylpiperidine-1-oxylradical (TEMPO)-oxidation and physical aqueous counter collision (ACC) methods The combination of TEMPO-oxidation and ACC is an efficient method to isolate CNFs by reducing chemical usage in TEMPO-oxidation and saving energy in ACC along with controlling the size of CNFs. Two cellulose sources, hardwood bleached kraft pulp (HW) and softwood bleached kraft pulp (SW), were used for the CNF isolation with different TEMPO oxidation time and a defined number of ACC pass. The CNF properties were investigated and compared in term of morphology, crystallinity index, transparency and birefringence.

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Article Synopsis
  • Cellulose nanofiber (CNF) is strong but short; this study develops a process to create longer cellulose fibers suitable for eco-friendly composites.
  • The method involves spinning, stretching, and drying CNF isolated from hardwood pulp using TEMPO oxidation, with varying spinning speeds and stretching ratios.
  • Results show these long fibers possess impressive mechanical properties, including a tensile modulus of 23.9 GPa and tensile strength of 383.3 MPa, indicating they are both strong and tough.
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Silica powder at nanoscale was obtained by heat treatment of Vietnamese rice husk following the sol-gel method. The rice husk ash (RHA) is synthesized using rice husk which was thermally treated at optimal condition at 600°C for 4 h. The silica from RHA was extracted using sodium hydroxide solution to produce a sodium silicate solution and then precipitated by adding H2SO4 at pH = 4 in the mixture of water/butanol with cationic presence.

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