,-Disubstituted Anilines Synthesis through Smiles Rearrangement.

Herein, we report a general and mild approach to effectively synthesize N-substituted anilines under metal-free conditions using sulfonyl chlorides and amines. Notably, this approach has shown a wide array of functional group tolerance, operational simplicity, and scalability, making it a useful tool for accessing ,-disubstituted anilines and functionalized products.