Pantropical tree rings show small effects of drought on stem growth.

Increasing drought pressure under anthropogenic climate change may jeopardize the potential of tropical forests to capture carbon in woody biomass and act as a long-term carbon dioxide sink. To evaluate this risk, we assessed drought impacts in 483 tree-ring chronologies from across the tropics and found an overall modest stem growth decline (2.5% with a 95% confidence interval of 2.

Growth-Mortality Coordination Differs Among Xerophytic Versus Mesophytic Tree Species During Severe Drought.

Forest composition is changing, yet the consequences for terrestrial carbon cycling are unclear. In the eastern United States, water-demanding "mesophytic" tree species are replacing "xerophytic" oaks (Quercus spp.) and hickories (Carya spp.

Changes in the western flank of the North Atlantic subtropical high since 1140 CE: Extremes, drivers, and hydroclimatic patterns.

Summer circulation and moisture patterns in the Southeast United States are controlled by the position of the North Atlantic subtropical high. In a warming climate, the subtropical high is projected to strengthen and expand west, but there remains uncertainty regarding its variability and linkages to natural drivers. Here, we use a tree-ring network across the Southeast United States to reconstruct the relative intensity of the pressure gradient across the subtropical high's western flank over the past 870 years.

Asymmetric effects of hydroclimate extremes on eastern US tree growth: Implications on current demographic shifts and climate variability.

Forests around the world are experiencing changes due to climate variability and human land use. How these changes interact and influence the vulnerability of forests are not well understood. In the eastern United States, well-documented anthropogenic disturbances and land-use decisions, such as logging and fire suppression, have influenced forest species assemblages, leading to a demographic shift from forests dominated by xeric species to those dominated by mesic species.

Long-term tropical cyclones activity shapes forest structure and reduces tree species diversity of U.S. temperate forests.

Increasing tropical cyclone (TC) pressure on temperate forests is inevitable under the recent global increase of the intensity and poleward migration of TCs. However, the long-term effects of TCs on large-scale structure and diversity of temperate forests remain unclear. Here, we aim to ascertain the legacy of TCs on forest structure and tree species richness by using structural equation models that consider several environmental gradients and use an extensive dataset containing >140,000 plots with >3 million trees from natural temperate forests across eastern United States impacted by TCs.

Warm springs alter timing but not total growth of temperate deciduous trees.

As the climate changes, warmer spring temperatures are causing earlier leaf-out and commencement of CO uptake in temperate deciduous forests, resulting in a tendency towards increased growing season length and annual CO uptake. However, less is known about how spring temperatures affect tree stem growth, which sequesters carbon in wood that has a long residence time in the ecosystem. Here we show that warmer spring temperatures shifted stem diameter growth of deciduous trees earlier but had no consistent effect on peak growing season length, maximum growth rates, or annual growth, using dendrometer band measurements from 440 trees across two forests.

Cross-biome synthesis of source versus sink limits to tree growth.

Uncertainties surrounding tree carbon allocation to growth are a major limitation to projections of forest carbon sequestration and response to climate change. The prevalence and extent to which carbon assimilation (source) or cambial activity (sink) mediate wood production are fundamentally important and remain elusive. We quantified source-sink relations across biomes by combining eddy-covariance gross primary production with extensive on-site and regional tree ring observations.

Joint effects of climate, tree size, and year on annual tree growth derived from tree-ring records of ten globally distributed forests.

Tree rings provide an invaluable long-term record for understanding how climate and other drivers shape tree growth and forest productivity. However, conventional tree-ring analysis methods were not designed to simultaneously test effects of climate, tree size, and other drivers on individual growth. This has limited the potential to test ecologically relevant hypotheses on tree growth sensitivity to environmental drivers and their interactions with tree size.

Recent increases in tropical cyclone precipitation extremes over the US east coast.

The impacts of inland flooding caused by tropical cyclones (TCs), including loss of life, infrastructure disruption, and alteration of natural landscapes, have increased over recent decades. While these impacts are well documented, changes in TC precipitation extremes-the proximate cause of such inland flooding-have been more difficult to detect. Here, we present a latewood tree-ring-based record of seasonal (June 1 through October 15) TC precipitation sums (ΣTCP) from the region in North America that receives the most ΣTCP: coastal North and South Carolina.

Palladium-Catalyzed Regioselective Arylation of Unprotected Allylamines.

Palladium-catalyzed organometallic transformations of free amines are often unsuccessful due to side reactions, such as oxidation, that can occur. However, the ability to furnish the free amine products from these reactions is important for improving the utility and sustainability of these processes, especially for accessing their potential as medicinal and agrochemical agents. Notably, the 3,3-diarylallylamine motif is prevalent in a variety of biologically relevant structures, yet there are few catalytic approaches to their synthesis, and none involving the free amine.

Linking drought legacy effects across scales: From leaves to tree rings to ecosystems.

Severe drought can cause lagged effects on tree physiology that negatively impact forest functioning for years. These "drought legacy effects" have been widely documented in tree-ring records and could have important implications for our understanding of broader scale forest carbon cycling. However, legacy effects in tree-ring increments may be decoupled from ecosystem fluxes due to (a) postdrought alterations in carbon allocation patterns; (b) temporal asynchrony between radial growth and carbon uptake; and (c) dendrochronological sampling biases.

Drought legacies are dependent on water table depth, wood anatomy and drought timing across the eastern US.

Severe droughts can impart long-lasting legacies on forest ecosystems through lagged effects that hinder tree recovery and suppress whole-forest carbon uptake. However, the local climatic and edaphic factors that interact to affect drought legacies in temperate forests remain unknown. Here, we pair a dataset of 143 tree ring chronologies across the mesic forests of the eastern US with historical climate and local soil properties.

Achieving Moderate Pressures in Sealed Vessels Using Dry Ice As a Solid CO2 Source.

Herein is presented a general strategy to perform reactions under mild to moderate CO2 pressures with dry ice. This technique obviates the need for specialized equipment to achieve modest pressures, and can even be used to achieve higher pressures in more specialized equipment and sturdier reaction vessels. At the end of the reaction, the vials can be easily depressurized by opening at room temperature.

Linking variation in intrinsic water-use efficiency to isohydricity: a comparison at multiple spatiotemporal scales.

Species-specific responses of plant intrinsic water-use efficiency (iWUE) to multiple environmental drivers associated with climate change, including soil moisture (θ), vapor pressure deficit (D), and atmospheric CO concentration (c ), are poorly understood. We assessed how the iWUE and growth of several species of deciduous trees that span a gradient of isohydric to anisohydric water-use strategies respond to key environmental drivers (θ, D and c ). iWUE was calculated for individual tree species using leaf-level gas exchange and tree-ring δ C in wood measurements, and for the whole forest using the eddy covariance method.

Drought timing and local climate determine the sensitivity of eastern temperate forests to drought.

Projected changes in temperature and drought regime are likely to reduce carbon (C) storage in forests, thereby amplifying rates of climate change. While such reductions are often presumed to be greatest in semi-arid forests that experience widespread tree mortality, the consequences of drought may also be important in temperate mesic forests of Eastern North America (ENA) if tree growth is significantly curtailed by drought. Investigations of the environmental conditions that determine drought sensitivity are critically needed to accurately predict ecosystem feedbacks to climate change.

Effects of the Boy Scouts of America Personal Fitness Merit Badge on Cardio-Metabolic Risk, Health Related Fitness and Physical Activity in Adolescent Boys.

A growing number of adolescents are more sedentary and have fewer formal opportunities to participate in physical activity. With the mounting evidence that sedentary time has a negative impact on cardiometabolic profiles, health related fitness and physical activity, there is a pressing need to find an affordable adolescent physical activity intervention. One possible intervention that has been overlooked in the past is Boy Scouts of America.

Human-mediated extirpation of the unique Chatham Islands sea lion and implications for the conservation management of remaining New Zealand sea lion populations.

While terrestrial megafaunal extinctions have been well characterized worldwide, our understanding of declines in marine megafauna remains limited. Here, we use ancient DNA analyses of prehistoric (<1450-1650 AD) sea lion specimens from New Zealand's isolated Chatham Islands to assess the demographic impacts of human settlement. These data suggest there was a large population of sea lions, unique to the Chatham Islands, at the time of Polynesian settlement.

Mountain pine beetle selectivity in old-growth ponderosa pine forests, Montana, USA.

A historically unprecedented mountain pine beetle (MPB) outbreak affected western Montana during the past decade. We examined radial growth rates (AD 1860-2007/8) of co-occurring mature healthy and MPB-infected ponderosa pine trees collected at two sites (Cabin Gulch and Kitchen Gulch) in western Montana and: (1) compared basal area increment (BAI) values within populations and between sites; (2) used carbon isotope analysis to calculate intrinsic water-use efficiency (iWUE) at Cabin Gulch; and (3) compared climate-growth responses using a suite of monthly climatic variables. BAI values within populations and between sites were similar until the last 20-30 years, at which point the visually healthy populations had consistently higher BAI values (22-34%) than the MPB-infected trees.