Publications by authors named "Changyong Chase Cao"

The development of lithium-sulfur (Li-S) batteries is hindered by lithium dendrite growth and slow sulfur redox kinetics. Here, we report a composite separator (CAFS) composed of nanocellulose fibers (NCF) and high-dielectric aluminum oxide (AlO) nanoparticles. The AlO component produces a directional electric field under external bias, anchoring bis(trifluoromethanesulfonyl)imide (TFSI) anions and promoting lithium salt dissociation, which enhances lithium-ion (Li) transport and stabilizes the anode.

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The incorporation of waterborne polyurethane (WPU) into bacterial cellulose (BC) fibers significantly improved the tensile strength of the resulting WPU/BC composite film, achieving an enhancement of 19.4 times. The formation of hydrogen bonds between WPU and BC effectively eliminates cavities within the BC matrix, achieving significant plasticization and toughening.

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The Earth's orbital environment is increasingly congested with space debris, posing a substantial risk to space operations and safety. Current mitigation strategies are primarily tailored to either small debris, through protective devices, or large debris, via spacecraft deorbiting methods, leaving medium-sized debris (0.4-10 cm) as a significant unaddressed threat.

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Lithium metal is considered one of the most promising anode materials for lithium batteries due to its high theoretical specific capacity (3860 mA h g) and low redox potential (-3.04 V). However, uncontrolled lithium dendrite growth and severe interfacial side reactions during cycling result in poor performance and safety risks, significantly limiting its practical applications.

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Article Synopsis
  • * This study explores how adding propylene glycol methyl ether (PM) and zinc iodide (ZnI) to the electrolyte improves the battery's performance by enhancing redox reactions and electron transfer.
  • * The combined effect of PM and the iodine/redox mediator allows the Zn-S battery to achieve a remarkable capacity of 1456 mAh/g and an energy density of 471.8 Wh/kg at a current density of 0.2 A/g.
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