The development of lithium-sulfur (Li-S) batteries is hindered by lithium dendrite growth and slow sulfur redox kinetics. Here, we report a composite separator (CAFS) composed of nanocellulose fibers (NCF) and high-dielectric aluminum oxide (AlO) nanoparticles. The AlO component produces a directional electric field under external bias, anchoring bis(trifluoromethanesulfonyl)imide (TFSI) anions and promoting lithium salt dissociation, which enhances lithium-ion (Li) transport and stabilizes the anode.
View Article and Find Full Text PDFPolymers (Basel)
March 2025
The incorporation of waterborne polyurethane (WPU) into bacterial cellulose (BC) fibers significantly improved the tensile strength of the resulting WPU/BC composite film, achieving an enhancement of 19.4 times. The formation of hydrogen bonds between WPU and BC effectively eliminates cavities within the BC matrix, achieving significant plasticization and toughening.
View Article and Find Full Text PDFThe Earth's orbital environment is increasingly congested with space debris, posing a substantial risk to space operations and safety. Current mitigation strategies are primarily tailored to either small debris, through protective devices, or large debris, via spacecraft deorbiting methods, leaving medium-sized debris (0.4-10 cm) as a significant unaddressed threat.
View Article and Find Full Text PDFLithium metal is considered one of the most promising anode materials for lithium batteries due to its high theoretical specific capacity (3860 mA h g) and low redox potential (-3.04 V). However, uncontrolled lithium dendrite growth and severe interfacial side reactions during cycling result in poor performance and safety risks, significantly limiting its practical applications.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
March 2025