Visible light-driven selective redirection of phenolic carbon in heterogeneous Fenton-like reaction.

Oxidative polymerization of phenolic pollutants by the heterogeneous Fenton-like reaction is a sustainable strategy for wastewater decontamination and recovery of carbonaceous resources. However, controlling the reaction pathway to selectively polymerize the phenolic pollutants is challenging. Herein, we used visible light to shift the reaction pathway from phenolic pollutants degradation (which often results in incomplete mineralization) to polymerization over a g-C₃N₄ catalyst deposited on a Cu₂O nanowire.

Piezocatalysis-combined advanced oxidation processes for organic pollutant degradation in water system.

The piezoelectric catalyst process has emerged as a promising technology for energy harvesting, effectively converting natural mechanical energies, such as wind, water flow, and waves, into usable electrical energy using piezoelectric materials. In recent years, there has been a growing interest in applying this technology to water treatment to address environmental challenges. Concurrently, research efforts have focused on enhancing the efficiency of piezoelectric catalysis by integrating it with advanced oxidation processes (AOPs).

Alternative assessment of machine learning to polynomial regression in response surface methodology for predicting decolorization efficiency in textile wastewater treatment.

This study investigated the potential of machine learning (ML) as a substitute for polynomial regression in conventional response surface methodology (RSM) for decolorizing textile wastewater via a UV/HO process. While polynomial regression offers limited adaptability, ML models provide superior flexibility in capturing nonlinear responses but are prone to overfitting, particularly with constrained RSM datasets. In this study, we evaluated decision tree (DT), random forest (RF), multilayer perceptron (MLP), and extreme gradient boosting (XGBoost) models with respect to a quadratic regression model.

Simple synthesis of K/P co-doped graphitic carbon nitride to enhance photocatalytic performance under simulated solar irradiation.

The doping or co-doping of graphitic carbon nitride (g-CN) with other elements is a useful modification technique that overcomes the disadvantages of the base material and enhances its photocatalytic performance. In this study, K and P were successfully incorporated into g-CN using a one-step, single-precursor (KHPO) synthesis method. The incorporation of K and P was confirmed using energy-dispersive X-ray spectrometry and wavelength-dispersive X-ray fluorescence spectrometry.

Evaluation of large-scale poultry manure-derived biochar for efficient cadmium removal in zinc smelter wastewater.

Cadmium (Cd), a carcinogen, is released from industrial activities like metal refineries and battery runoff, with significant contamination reported near zinc smelters in Korea. This study addresses the issue using an efficient, economical adsorption process with waste-derived biochar-based adsorbents known for high Cd removal. Poultry manure (PM), typically used as fertilizer, can lead to environmental pollution if mismanaged; therefore, it was pyrolyzed to produce biochar.

Harnessing wood bottom ash for efficient arsenic removal from wastewater: Adsorption mechanisms and process optimisation.

This study explored the innovative application of wood bottom ash (WBA) as an adsorbent for arsenic (As) removal from wastewater, focusing on the adsorption mechanism and optimisation of the operational conditions. Comprehensive spectroscopic analyses, including FE-SEM/EDS, BET, XRF, XRD, FT-IR, and XPS, were performed to examine the elemental and mineralogical changes in WBA before and after As adsorption. The study assessed the adsorption kinetics and isotherms, revealing that As adsorption reached equilibrium within 48 h, with a maximum capacity of 121.

Efficient cadmium removal from industrial wastewater generated from smelter using chemical precipitation and oxidation assistance.

The effective treatment of cadmium (Cd) in smelting wastewater is of great industrial importance. This study investigates the efficient removal of Cd from real industrial smelting wastewater via chemical precipitation using a series of experiments. In particular, the effects of different precipitants, agitation conditions, and the addition of NaOCl on Cd removal and pH variation are investigated.

Feasibility study of Aesculus turbinata fruit shell-derived biochar for ammonia removal in wastewater and its subsequent use as nitrogen fertilizer.

In the face of increasing nitrogen demand for crop cultivation driven by population growth, this study presents a sustainable solution to address both the heightened demand and the energy-intensive process of nitrogen removal from wastewater. Our approach involves the removal of nitrogen from wastewater and its subsequent return to the soil as a fertilizer. Using biochar derived from Aesculus turbinata fruit shells (ATFS), a by-product of post-medical use, we investigated the effect of pyrolysis temperature on the NH-N adsorption capacity of ATFS biochar (ATFS-BC).

Graphitic-carbon-nitride-hydrophilicity-dependent photocatalytic degradation of antibiotics with different log K.

The surface hydrophilicity of a photocatalyst is an important factor that directly influences its interactions with organic pollutants and significantly impacts its degradation. In this study, we investigated the impact of increased hydrophilicity of g-CN (CN) by alkaline solvothermal treatment on the degradations of three antibiotics (oxytetracycline (OTC), oxolinic acid (OA), and sulfamethoxazole (SMX)) with different log K values. Scanning electron microscopy (SEM), X-ray diffraction analysis (XRD), and Fourier-transform infrared (FT-IR) spectroscopy showed no significant differences in the morphology, crystalline structure, and surface functional groups of CN after alkaline solvothermal treatment (Nv-HPCN).

Use of thermally activated Fenton sludge for Cd removal in zinc smelter wastewater: Mechanism and feasibility of Cd removal.

Fenton sludge is a byproduct of the Fenton process that contains large amounts of Fe and Ca. Because of the secondary contamination generated during the disposal of this byproduct, ecofriendly treatment methods are needed. In this study, we used Fenton sludge to remove the Cd discharged from a zinc smelter factory, using thermal activation to enhance the Cd adsorption capacity.

Cycling of phosphorus from wastewater to fertilizer using wood ash after energy production.

Quercus wood was used for thermal energy production, and wood bottom ash (WDBA) was used as a medium for water purification and soil fertilizer in accordance with the recently proposed food-water-energy nexus concept. The wood contained a gross calorific value of 14.83 MJ kg, and the gas generated during thermal energy production has the advantage of not requiring a desulfurization unit due to its low sulfur content.

Value-added application of cattle manure bottom ash for phosphorus recovery from water and replenishment in soil.

This study addresses ways to circulate the flow of phosphorus (P) from water to soil to improve water quality and provide a sustainable supply of P into soil. Here, bottom ash (BA_CCM), the byproduct of the combustion of cattle manure, which is performed for obtaining energy, was used to remove P in wastewater. Next, the P-captured BA_CCM was used as P fertilizer for rice growth.

Facile synthesis of N vacancy g-CN using Mg-induced defect on the amine groups for enhanced photocatalytic •OH generation.

Photocatalysis offers opportunities to degrade recalcitrant organic pollutants without adding treatment chemicals. Nitrogen (N) vacancy is an effective point-defect engineering strategy to mitigate electron-hole recombination and facilitate hydroxyl radical (•OH) production via superoxide radical (O) generation during photocatalytic application of graphitic carbon nitride (g-CN). Here, we report a novel strategy for fabrication of N-vacancy-rich g-CN (NvrCN) via post-solvothermal treatment of Mg-doped g-CN.

Effect of water filtration infrared-A (wIRA) sauna on inorganic ions excreted through sweat from the human body.

Sweat discharged as a result of exposure to sauna plays an important role in removing inorganic ions accumulated in the body, including heavy metals. In this study, inorganic ions (toxic and nutrient elements) excreted in the form of sweat from the body using a water-filtered infrared-A (wIRA) sauna were determined using inductively coupled plasma sector field mass spectrometry. The analyzed elements included eight toxic elements (Al, As, Be, Cd, Ni, Pb, Ti, and Hg) and 10 nutrient elements (Ca, Co, Cr, Cu, Fe, Mg, Mn, Se, V, and Zn), and their correlations were determined.

Application of response surface methodology and artificial neural network for the preparation of Fe-loaded biochar for enhanced Cr(VI) adsorption and its physicochemical properties and Cr(VI) adsorption characteristics.

In this study, we optimized and explored the effect of the conditions for synthesizing Fe-loaded food waste biochar (Fe@FWB) for Cr(VI) removal using the response surface methodology (RSM) and artificial neural network (ANN). The pyrolysis time, temperature, and Fe concentration were selected as the independent variables, and the Cr(VI) adsorption capacity of Fe@FWB was maximized. RSM analysis showed that the p-values of pyrolysis temperature and Fe concentration were less than 0.

Application of calcium-rich mineral under nonwoven fabric mats and sand armor as cap layer for interrupting N and P release from river sediments.

This work investigates the applicability of thermally treated calcium-rich minerals (CRMs), such as sepiolite (SPL), attapulgite (ATT), and dolomite (DLM) to hinder the nitrogen (N) and phosphorus (P) release from river sediments. A non-woven fabric mat (NWFM) or a sand layer were also capped as armor layers, i.e.

Phosphorus recovery from cattle manure bottom ash by extraction and precipitation methods.

Phosphorus, a limiting element, is essential for living organisms, but the total amount available is decreasing with its increasing use. This problem can be solved by studying the methods of phosphorus recovery from waste. Phosphorus (PO, 13.

Restoring phosphorus from water to soil: Using calcined eggshells for P adsorption and subsequent application of the adsorbent as a P fertilizer.

This study investigated the solution for two environmental issues: excess of P in water and its deficiency in soil, which is restored by transferring the adsorbed P from water into the soil using eggshell as an adsorbent. The eggshells were calcined at different temperatures to improve their adsorption capacity, and evaluated for their physical/chemical properties and P adsorption capacity. The eggshells calcined at 800 °C (CES-800) had the highest P adsorption; CaCO decomposed into 23.

Conversion of cattle manure into functional material to remove selenate from wastewater.

Herein, pyrolysis of cattle manure was conducted to synthesize an effective material for removing heavy metals (e.g., selenium) from water environments.

Bisphenol A degradation using waste antivirus copper film with enhanced sono-Fenton-like catalytic oxidation.

This study investigated the applicability of waste antivirus copper film (CF) as a Fenton-like catalyst. The reaction activity of HO and CF in combination was significantly enhanced by ultrasound (US) irradiation, and the synergy factor calculated from bisphenol A (BPA) degradation using CF-HO-US was 9.64 compare to that of dual factors.

Fluoride removal by thermally treated egg shells with high adsorption capacity, low cost, and easy acquisition.

In this study, the use of eggshells was suggested as an adsorbent for fluoride removal, and their mechanism of fluoride removal was investigated. The eggshells underwent thermal treatment to improve their adsorption capacity; 800 °C was found to be the optimal temperature for treatment. Eggshells thermally treated at 800 °C (ES-800) were mainly composed of Ca (82.