Curing Mechanism of Hydroxyl-Terminated Polybutadiene (HTPB) Formulated with Isophorone Diisocyanate (IPDI) as Revealed Using Raman Spectroscopy.

Hydroxyl-terminated polybutadiene (HTPB) is used in a variety of formulations, particularly for military and aerospace applications as a binder for energetic materials. This work investigates details of its curing process when formulated with isophorone diisocyanate (IPDI). Raman spectroscopy was used as a fast, sensitive, non-destructive technique to monitor the curing process of HTPB-IPDI.