41 results match your criteria: "PSN College of Engineering and Technology[Affiliation]"

Today COVID-19 pandemic articulates high stress on clinical resources around the world. At present, physical and viral tests are slowly emerging, and there is a need for robust pandemic detection that biomedical sensors can aid. The utility of biomedical sensors is correlated with the medical instruments with physiological metrics.

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This research study uses Artificial Neural Networks (ANNs) to predict occupational accidents in Sivakasi firework industries. Atmospheric temperature, pressure and humidity are the causes of explosion during chemical mixing, drying, and pellet making. The Proposed ANN model predicts the accidents and the session of accidents (FN/AN) based on atmospheric conditions.

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Researchers have mentioned the importance of digitization in improving efficiency and productivity in Small and Medium Enterprises (SME). Fortunately, there is no proof that Digitization can be used to deal with the outcome of severe incidents like COVID-19. The research paper suggested that the increased rate of SMEs has increased significantly.

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Galectin-1 (Gal-1) is the first member of galectin family, which has a carbohydrate recognition domain, specifically binds towards -galactoside containing oligosaccharides. Owing its association with carbohydrates, Gal-1 is involved in many biological processes such as cell signaling, adhesion and pathological pathways such as metastasis, apoptosis and increased tumour cell survival. The development of β-galactoside based inhibitors would help to control the Gal-1 expression.

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Pyridyl/hydroxyphenyl versus carboxyphenyl anchoring moieties in Zn - Thienyl porphyrins for dye sensitized solar cells.

Spectrochim Acta A Mol Biomol Spectrosc

January 2020

Centre for Scientific and Applied Research, PSN College of Engineering and Technology, Melathediyoor, Tirunelveli 627 152, India. Electronic address:

For developing efficient DSCs, anchoring moieties need to be understood in detail with respect to a particular dye. Herein, we have synthesized new Zn-thienyl porphyrin dyes based on pyridyl and hydroxyphenyl anchors and compared with traditional carboxyphenyl anchoring group. The effect of such variation in anchoring groups was investigated with UV-vis and fluorescence spectroscopy as well as electrochemical studies.

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A review on applications of chitosan-based Schiff bases.

Int J Biol Macromol

May 2019

Centre for Scientific and Applied Research, PSN College of Engineering and Technology (Autonomous), Tirunelveli 627152, Tamil Nadu, India. Electronic address:

Biopolymers have become very attractive as they are degradable, biocompatible, non-toxic and renewable. Due to the intrinsic reactive amino groups, chitosan is vibrant in the midst of other biopolymers. Using the versatility of these amino groups, various structural modifications have been accomplished on chitosan through certain chemical reactions.

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This research aims to combine the effects of nanosilica and glass powder on the properties of self-compacting mortar at normal and at higher temperatures. The fine aggregate was replaced by waste glass powder at various percentage levels of 10%, 20%, 30%, 40% and 50%. The mechanical properties of self-compacting glass mortar (SGCM) were studied at elevated temperatures of 200, 400, 600 and 800 °C.

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Tin(IV) porphyrin scaffolds having long-chain (C and C) alkoxyphenyl group at one position were synthesized with axial dichloro and dihydroxo ligands. Modifications with respect to the alkoxy chain length and the axial ligands were investigated using UV-vis and fluorescence spectroscopy as well as cyclic voltammetry. Significantly higher molar absorption coefficients were noted with dichloro axial ligands whereas higher fluorescence quantum yields were observed for C alkoxy chain substituents.

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Meningioma is the one of the most common type of brain tumor, it as arises from the meninges and encloses the spine and the brain inside the skull. It accounts for 30% of all types of brain tumor. Meningioma's can occur in many parts of the brain and accordingly it is named.

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In this work, Zn-porphyrin with a hydantoin anchor (ZnPHy) was designed and synthesized for dye-sensitized solar cell (DSC) applications. The synthesized ZnPHy was well characterized using IR, NMR and mass spectral techniques, and satisfactory results were obtained. Cyclic voltammetry, UV-visible absorption, steady-state fluorescence, time-resolved fluorescence and transient absorption spectroscopic techniques were employed to elucidate the electrochemical and photophysical properties of ZnPHy.

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Crystal structure of 5-tert-but-yl-10,15,20-tri-phenyl-porphyrin.

Acta Crystallogr E Crystallogr Commun

February 2016

School of Chemistry, SFI Tetrapyrrole Laboratory, Trinity Biomedical Sciences Institute, 152-160 Pearse Street, Trinity College Dublin, The University of Dublin, Dublin 2, Ireland.

In the title free base porphyrin, C42H34N4, the neighbouring N⋯N distances in the center of the ring vary from 2.818 (8) to 2.998 (8) Å and the phenyl rings are tilted from the 24-atom mean plane at angles varying between 62.

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Novel bio-essential metal based complexes linked by heterocyclic ligand: Synthesis, structural elucidation, biological investigation and docking analysis.

J Photochem Photobiol B

January 2016

Research Department of Chemistry, VHNSN College, Virudhunagar 626 001, Tamilnadu, India. Electronic address:

New series of bio-essential metal based complexes linked by Schiff base ligand (L) and 2,2'-bipyridine (bpy) have been synthesized and characterized by diverse spectral techniques such as elemental analysis, magnetic susceptibility, molar conductivity measurements, FT-IR, UV-Vis., (1)H NMR, (13)C NMR, EPR and Mass. The spectral data suggest that the metal complexes espouse octahedral geometry around the metal ions.

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Providing authentication and integrity in medical images is a problem and this work proposes a new blind fragile region based lossless reversible watermarking technique to improve trustworthiness of medical images. The proposed technique embeds the watermark using a reversible least significant bit embedding scheme. The scheme combines hashing, compression, and digital signature techniques to create a content dependent watermark making use of compressed region of interest (ROI) for recovery of ROI as reported in literature.

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Chitosan (a biopolymer) anchored Cu(II) and Ni(II) Schiff base complexes, [M(OIAC)Cl2] (M: Cu/Ni and OIAC: ([2-oxo-1H-indol-3-ylidene]amino)chitosan) were electron beam irradiated by different doses (100 Gy, 1 kGy and 10 kGy). The electron beam has shown potential impact on biopolymer's support, in detail chain linking and chain scissoring, as evidenced by viscosity studies, FT-IR and X-ray diffraction spectroscopic techniques. Due to these structural changes, thermal properties of the complexes were found to be changed.

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This study was carried out to investigate the effect of electron beam irradiation on the spectral and catalytic properties of chitosan supported (ONClCl) tetra coordinated Co(II) complex, [Co(OIAC)Cl2]. The complex was subjected to electron beam irradiation of 100 Gy, 1 kGy and 10 kGy doses. Chain scission of chitosan was observed on irradiation at 100 Gy and 10 kGy and chain linking at 1 kGy as evidenced by viscosity and FT-IR spectroscopic studies.

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Three novel quadridentate Schiff base complexes, [Cu(OIAC)Cl(2)], [Co(OIAC)Cl(2)] and [Ni(OIAC)Cl(2)] [OIAC, a Schiff base ligand: (([2-oxo-1H-indol-3-ylidene]amino)chitosan)] have been synthesized. The molecular structure of the complexes has been characterised by elemental analyses, magnetic measurements, molar conductance studies, vibrational (FT-IR), electronic (UV-Vis) and (1)H NMR spectroscopic techniques. Thermal properties of the complexes have been investigated with TG-DTG analyses.

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