Pilot-Scale Electrospinning of PLA Using Biobased Dyes as Multifunctional Additives.

Fibers with diameters in the lower micrometer range have unique properties suitable for applications in the textile and biomedical industries. Such fibers are usually produced by solution electrospinning, but this process is environmentally harmful because it requires the use of toxic solvents. Melt electrospinning is a sustainable alternative but the high viscosity and low electrical conductivity of molten polymers produce thicker fibers.

The Effect of Electrical Polarity on the Diameter of Biobased Polybutylene Succinate Fibers during Melt Electrospinning.

Melt electrospinning is a simple, versatile, and widely used technique for the production of microfibers and sub-microfibers. Polybutylene succinate (PBS) is a promising raw material for the preparation of melt-electrospun fibers at the laboratory scale. The inclusion of additives in the PBS melt can reduce the final fiber diameter, but economically feasible larger-scale processes remain challenging.

A Porphyrin-Based Organic Network Comprising Sustainable Carbon Dots for Photopolymerization.

Sustainable carbon dots (CDs) based on furfuraldehyde (F-CD) resulted in a photosensitive material after pursuing the Alder-Longo reaction. The porphyrin moiety formed connects the F-CDs in a covalent organic network. This heterogeneous material (P-CD) was characterized by XPS indicating incorporation of the respective C, N and O moieties.

Textile Strain Sensor Enhancement by Coating Metal Yarns with Carbon-Filled Silicone.

Flexible and stretchable strain sensors are an important development for measuring various movements and forces and are increasingly used in a wide range of smart textiles. For example, strain sensors can be used to measure the movements of arms, legs or individual joints. Thereby, most strain sensors are capable of detecting large movements with a high sensitivity.

How Does Mental Workload Influence the Adoption of Clinical Information Systems: An Exploratory Study.

Mental workload and technology acceptance are relevant factors that relate to use behavior and performance. Studies show a potential moderating effect of mental workload on predictors of technology acceptance. Aim of this study was the investigation of predictors of technology acceptance (UTAUT) related to clinical information systems and their relation to mental workload.

A machine learning approach to identify risk factors for running-related injuries: study protocol for a prospective longitudinal cohort trial.

Background: Running is a very popular sport among both recreational and competitive athletes. However, participating in running is associated with a comparably high risk of sustaining an exercise-related injury. Due to the often multifactorial and individual reasons for running injuries, a shift in thinking is required to account for the dynamic process of the various risk factors.

Sustainable Afterglow Room-Temperature Phosphorescence Emission Materials Generated Using Natural Phenolics.

Long-lived afterglow room-temperature phosphorescence (RTP) from natural phenolics has seldom been reported yet this is essential for the development of sustainable afterglow RTP materials. With this research, we have prepared sustainable afterglow RTP materials (GA@SA) with a lifetime of up to ≈934.7 ms by embedding gallic acid (GA) within a Ca -crosslinked sodium alginate (SA) matrix.

Activation and Stabilization of Lipase B from Candida antarctica by Immobilization on Polymer Brushes with Optimized Surface Structure.

A reusable support system for the immobilization of lipases is developed using hybrid polymer-inorganic core shell nanoparticles. The biocatalyst core consists of a silica nanoparticle. PMMA is grafted from the nanoparticle as polymer brush via ARGET ATRP (activator regenerated by electron transfer atom transfer radical polymerization), which allows defining the surface properties by chemical synthesis conditions.

Enzymatic synthesis of novel aromatic-aliphatic polyesters with increased hydroxyl group density.

Background: Polyesters with pendant hydroxyl groups are attractive materials which offer additional functionalization points in the polymer chain. In contrast to chemical polycondensation, lipase regioselectivity enables the synthesis of these materials as certain hydroxyl groups remain unaffected during the enzymatic process.

Methods And Major Results: In this study, a combination of synthesis development and reactor design was used for the enzymatic synthesis of an aliphatic-aromatic polyester with two different classes of pendant hydroxyl groups.

Coating of Silicone Monofilaments with Elastic Carbon Black-Silver-Silicone Layers and Their Characterization Especially with Regard to the Change of the Electrical Resistance in Dependence on Strain.

Smart textiles have properties that outperform the conventional protective and decorative function of textiles. By integrating special sensors into clothing, body functions and movements can be detected. Piezoresistive sensors measure a change in electrical resistance due to the application of force in the form of stretching, pressure or bending.

Curcumin and Silver Doping Enhance the Spinnability and Antibacterial Activity of Melt-Electrospun Polybutylene Succinate Fibers.

Melt electrospinning is a polymer processing technology for the manufacture of microfibers and nanofibers. Additives are required to reduce the melt viscosity and increase its conductivity in order to minimize the fiber diameter, and can also impart additional beneficial properties. We investigated the preparation of polybutylene succinate (PBS) microfibers incorporating different weight percentages of two multifunctional additives (the organic dye curcumin and inorganic silver nanoparticles) using a single-nozzle laboratory-scale device.

Leg length discrepancy: A systematic review on the validity and reliability of clinical assessments and imaging diagnostics used in clinical practice.

Background: A variety of assessments to determine leg length discrepancy (LLD) is used in clinical practice and evidence about validity and reliability may differ.

Objective: The objective of this systematic review was to identify and describe the validity and reliability of different assessments and imaging diagnostics for the determination of LLD.

Materials And Methods: The review was conducted following the recommendations of Preferred Reporting Items for Systematic reviews and Meta-Analyses (PRISMA).

Polyester Fabric with Fluorescent Properties Using Microwave Technology for Anti-Counterfeiting Applications.

The article presented concerns the application of fluorescein as a fluorescent material for anti-counterfeiting technology which will allow the labeling and identification of legitimate articles in the textile field. Fluorescein has been applied to polyester fabrics by microwave irradiation technique in the presence of a UV absorber. Thus, its presence in the textile substrate is detectable following an excitation at a specific wavelength belonging to the Ultra-violet zone, which makes this material very effective for tracking and detecting counterfeit articles.

ICD-11 extension codes support detailed clinical abstraction and comprehensive classification.

Background: The new International Classification of Diseases-11th revision (ICD-11) succeeds ICD-10. In the three decades since ICD-10 was released, demands for detailed information on the clinical history of a morbid patient have increased.

Methods: ICD-11 has now implemented an addendum chapter X called "Extension Codes".

Effect of Organic Solvents on the Structure and Activity of a Minimal Lipase.

Lipases are ubiquitously used in chemo-enzymatic synthesis and industrial applications. Nevertheless, the modulation of the activity of lipases by organic solvents still is not fully understood at the molecular level. We systematically investigated the activity and structure of lipase A from in binary water-organic solvent mixtures of dimethyl sulfoxide (DMSO), acetonitrile (ACN), and isopropyl alcohol (IPA) using activity assays, fluorescence spectroscopy, molecular dynamics (MD) simulations, and FRET/MD analysis.

Comparison of Plantar Sensitivity, Dynamic Balance, and Lower Extremity Joint Range of Motion Between Experienced Female Ballet Dancers and Female Non-Dancing Athletes: A Cross-Sectional Study.

Objectives: Ballet dancers may increasingly use plantar sensory feedback to control foot position and movement during dance activities. Balance and joint range of motion (ROM) are important factors in ballet and may be related to plantar sensation in ballet dancers. Data on related functions of female ballet dancers compared to female non-dancing athletes are sparse.

Fortifying a meal with oyster mushroom powder beneficially affects postprandial glucagon-like peptide-1, non-esterified free fatty acids and hunger sensation in adults with impaired glucose tolerance: a double-blind randomized controlled crossover trial.

Purpose: Impaired glucose tolerance (IGT) is a pathophysiological condition characterized by insulin resistance with known metabolic consequences such as postprandial hyperglycemia and hypertriglyceridemia. We hypothesized that fortifying a meal with mushrooms rich in β-glucans may diminish glucose and triglyceride responses by improving postprandial gastrointestinal hormone release.

Methods: In a randomized controlled crossover study, 22 subjects with IGT ingested a meal either enriched with 20 g powder (8.

Attitudes towards working in retirement: a latent class analysis of older workers' motives.

One of the fastest growing labour market groups is working pensioners, meaning those who work past the statutory retirement age whilst receiving a pension. Previous research has investigated the motives of this group and found very heterogeneous reasons for employment in retirement. However, little is known about the expectations and preferred work arrangements of older workers regarding a potential post-retirement employment.

Clinical Outcomes of Advanced-Stage Cutaneous Lymphoma under Low-Dose Gemcitabine Treatment: Real-Life Data from the German Cutaneous Lymphoma Network.

Background: Gemcitabine is an effective single-agent chemotherapy used in advanced stages of cutaneous T-cell lymphoma (CTCL). However, gemcitabine used in the current standard regimen is frequently associated with adverse events (AE), such as an increased risk for myelosuppression and severe infections.

Objectives: We investigated in this retrospective study the effect of low-dose gemcitabine in pretreated advanced-stage CTCL and in blastic plasmacytoid dendritic cell neoplasia (BPDCN) regarding overall response (OR), progression-free survival (PFS), and AE.

Rational Selection of Cyanines to Generate Conjugate Acid and Free Radicals for Photopolymerization upon Exposure at 860 nm.

Different cyanines absorbing in the NIR between 750 and 930 nm were applied to study the efficiency of both radical and cationic polymerization in combination with diaryliodonium salt. Variation of the connecting methine chain and structure of the terminal indolium moiety provided a deeper insight in the structure of the cyanine NIR-sensitizer and the efficiency to generate initiating radicals and conjugate acid. Photophysical studies were pursued by fluorescence spectroscopy providing a deeper understanding regarding the lifetime of the excited state and contribution of nonradiative deactivation resulting in generation of additional heat in the polymerization process.

Examining the Mental Workload Associated With Digital Health Technologies in Health Care: Protocol for a Systematic Review Focusing on Assessment Methods.

Background: The workload in health care is high; physicians and nurses report high stress levels due to a demanding environment where they often have to perform multiple tasks simultaneously. As a result, mental health issues among health care professionals (HCPs) are on the rise and the prevalence of errors in their daily tasks could increase. Processes of demographic change are partly responsible for even higher stress levels among HCPs.

Development of Flexible and Functional Sequins Using Subtractive Technology and 3D Printing for Embroidered Wearable Textile Applications.

Embroidery is often the preferred technology when rigid circuit boards need to be connected to sensors and electrodes by data transmission lines and integrated into textiles. Moreover, conventional circuit boards, like Lilypad Arduino, commonly lack softness and flexibility. One approach to overcome this drawback can be flexible sequins as a substrate carrier for circuit boards.

Metoprolol and Its Degradation and Transformation Products Using AOPs-Assessment of Aquatic Ecotoxicity Using QSAR.

Pharmaceuticals are found in waterbodies worldwide. Conventional sewage treatment plants are often not able to eliminate these micropollutants. Hence, Advanced Oxidation Processes (AOPs) have been heavily investigated.