Graphene oxide decoration with ZnAl LDH and further functionalization with APTES for enhancing the toughness of polyurethane coatings.

The primary goal of this study is the enhancement of the mechanical properties of polyurethane (PU) coating via introducing a hybrid sandwich-like nanofiller composed of layered double hydroxide (LDH) grown on graphene oxide. To increase the nanofiller compatibility with the PU matrix, its surface was functionalized with an amino-functional silane coupling agent(APTES). Characterization of the particles with Raman, TGA, EDX-mounted FESEM, XRD approved the prosperous synthesis and modification of the nanosheets.

Fabrication of an inorganic-organic hybrid based on lanthanum and trigonella grandiflora extract as an innovative corrosion inhibitor.

This work presents a new and efficient biobased hybrid hinge based on lanthanum (La) cations and trigonella grandiflora (TG) extract, represented as La@TG, in a 3.5% NaCl solution, as an organic/inorganic mild steel corrosion inhibitor. The concentration of La cations and TG components released into the solution at various pH levels was assessed using UV-Vis/ICP-OES analysis.

Multi-metal/ligand MOFs: Transformative materials for energy storage, photocatalysis, and sensor technologies.

Metal-organic frameworks (MOFs) are a highly versatile class of materials that have attracted considerable attention because of their unique structural tunability and broad range of applications. The introduction of multiple metals and ligands into the MOF structures has emerged as an effective strategy to enhance their properties and expand their application range. Mixed-metal MOFs incorporate metals with varying oxidation states or coordination environments, thereby improving properties such as stability, porosity, and catalytic activity.

Effects of Polystyrene Nanoplastics on Oxidative Stress, Blood Biochemistry, and Digestive Enzyme Activity in Goldfish ().

Plastic pollution in aquatic ecosystems has become a global concern, and nanoplastics, due to their small size and high penetration potential, pose significant risks to aquatic organisms. This study aimed to evaluate the effects of polystyrene nanoplastics (PS-NPs) on oxidative stress biomarkers, blood biochemical parameters, and digestive enzyme activities in Goldfish (). The experiment was conducted over 21 days, exposing fish to four different dietary concentrations of PS-NPs (0, 1, 10, and 100 mg/Kg).

Enhancing NiAl-LDH@TiO-Tiv-S photoelectrocatalyst performance for textile dye degradation and oxygen production: S-doped Ti vacancies.

In this study, a novel approach is presented to overcome the drawbacks of titanium dioxide (TiO) as a semiconductor photocatalyst which has rapid charge carrier recombination as well as low visible-light response. These drawbacks lead to the decline of its performance in photocatalytic applications. For this purpose, sulfur (S) was incorporated into Ti structural vacancies (Tiv) by using a vacancy capture method.

Effect of coating fillers with HEMA-phosphate copolymer on the mechanical properties of an experimental composite resin.

Background: The water sorption and hydrolysis of silane over time can compromise the filler-resin matrix interface and cause the mechanical degradation of composite resins. The use of hydrophobic polymers for the surface treatment of fillers may improve the mechanical properties and durability of composites.

Objectives: The present study aimed to assess the effect of the surface treatment of fillers with hydroxyethyl methacrylate (HEMA)-phosphate copolymer on the mechanical properties of an experimental composite resin.

Formulation and characterization of BBR loaded niosomes using saponin as a nonionic biosurfactant investigating synergistic effects to enhance antibacterial activity.

This study aimed to enhance the antibacterial efficacy of BBR, a natural alkaloid with limited bioavailability and solubility, by encapsulating it in niosomes using saponin as a biosurfactant. Niosomes, non-ionic surfactant-based vesicles, improve drug stability and targeted delivery. The niosomes were synthesized using a ball milling-assisted method to optimize particle size and encapsulation efficiency.

Study on the Antibacterial Properties and Optical Characteristics of Clear Orthodontic Aligners Coated With Zinc Oxide and Magnesium Oxide Nanoparticles.

Objectives: This study aimed to evaluate and compare the antibacterial properties and optical characteristics of clear orthodontic aligners coated with zinc oxide (ZnO) and magnesium oxide (MgO) nanoparticles.

Materials And Methods: In this experimental laboratory study, polyethylene terephthalate glycol (PETG) aligner samples were coated with nanoparticles of ZnO, MgO and a combination of both (ZnO + MgO). The surface coatings were analysed before and after stability testing using field emission scanning electron microscopy (FESEM).

Photo-thermal conversion properties of MXene/metal-organic-frameworks-based nanofluids for solar energy harvesting.

This study focuses on enhancing solar energy capture efficiency by introducing innovative hybrid nanofluids for use in solar thermal collectors, whose performance largely depends on the absorption properties of the working fluid. The newly developed hybrid nanofluids, MXene/NH2-UiO66 (Zr) (noted as MX/UO66) and MXene/MIL-88B (Fe) (noted as MX/ML88), were synthesized using an in-situ solvothermal method, combining annealed Ti3C2Tx MXenes with water-stable metal-organic frameworks (MOFs). These nanofluids achieved high efficiency at low concentrations, providing both economic and performance benefits.

Developing a New Method of Transformation for Obtaining XYZ Color Values from RGB Images for Agricultural Applications.

The extraction of device-independent color values from affordable and accessible digital images based on a standard color space system is crucially necessary for agricultural applications, where color information for plant monitoring or diagnostics is required. This study aimed to develop a transformation matrix for obtaining XYZ color coordinates from the RGB values of digital images for agricultural applications. The calibration procedure was based on Munsell and Macbeth color charts.

TiCT MXene/MoS hybrid nanocomposites for synergistic smart corrosion protection of epoxy coatings.

MXene nanosheets have recently become a focus of research for corrosion protection due to their two-dimensional, sheet-like structure and distinct physicochemical characteristics. Nevertheless, their susceptibility to restacking and oxidation restricts their practical applications. To address this, the study proposes a custom hybrid structure by growing molybdenum disulfide (MoS) nanoparticles on the TiC MXene nanosheets (MX/MS) to prevent oxidation and restacking.

Electrophoretic deposition of chitosan/gelatin/hydroxyapatite nanocomposite coatings on 316 L stainless steel for biomedical applications.

In addition to the basic and main parts of hospital equipment, 316 L stainless steel is widely utilized in futures such as nails and screws, wires and medical bone clips, dental implants, heart springs (stents), needles, surgical scissors, etc. In the present study, the electrophoretic deposition of a composite based on chitosan (CS), gelatin, nano and microparticles of hydroxyapatite on a 316 L stainless steel substrate was investigated. Hydroxyapatite particles are added to it due to the ossification abilities of steel and due to an enhanced adhesion and bone production, CS and biocompatible gelatin polymer particles were also added to hydroxyapatite.

3D Pt@ZnAl-LDH catalyst on low-grade charcoal: A novel electrochemical platform for efficient textile dye degradation and glycerol oxidation.

The development of sustainable and efficient electrochemical processes is crucial for addressing global challenges related to water scarcity. In this study, we present a novel 3D core-shell electrocatalyst, Pt@ZnAl-LDH, supported on low-grade charcoal (LGC), which exhibits exceptional electrocatalytic activity for the degradation and decolorization of dye and the electrocatalytic conversion of glycerol to valuable C chemicals. The electrocatalytic degradation of methylene blue dye from water was investigated with a focus on the impact of temperature, pH, and dye concentration.

Integration of metal co-dopted cysteine builted in porous covalent organic framework (COF) decorated 2D hexagonal boron nitride (h-BN) for multi-functional smart coatings.

Advanced multi-functional epoxy coating with physical barrier/shielding against corrosive species, self-repairing-capability/active anti-corrosive behavior, abrasion resistance, and thermomechanical durability was established in this study. For this purpose, zinc/l-cysteine (ZC) inbuilt pH-sensitive covalent organic framework (COF) decorated two dimensional (2D) layered amino-functionalized (Si) oxidized hexagonal boron nitride (ZC-COF-Si-Oh-BN) container was prepared. Different analyses such as FT-IR, XRD, BET, XPS, TGA, TEM, and FE-SEM were utilized to evaluate the synthesized containers and pristine materials.

Chitosan adorned with ZIF-67 on ZIF-8 biocomposite: A potential LED visible light-assisted photocatalyst for wastewater decontamination.

The current investigation has utilized a simple and constructive stratified method to synthesize a binary (Cs/Z-8: chitosan (Cs) and zeolitic imidazolate framework-8 (Z-8)) and ternary Cs/Z-8/Z-67 (Z-67: ZIF-67) biocomposites at room temperature. A certain amount of Cs/Z-8 (0.05, 0.

In Vitro Effect of Anodization of Titanium Abutments on Color Parameters and Color Difference of Lithium Disilicate All-Ceramic Crowns.

Objective: This study assessed the effect of the anodization of titanium abutments on the color parameters and color difference of lithium disilicate (LDS) all-ceramic crowns.

Materials And Methods: In this study, 19 straight abutments were divided into two groups: anodized (n = 9) and non-anodized control (n = 9), with one hybrid zirconia abutment as a reference. Anodization was achieved by applying 63 V energy using seven 9 V flat batteries in series, with an electrolyte solution comprising 1 g trisodium phosphate in 250 mL distilled water for 5 s, resulting in a gold-yellow color.

Discovery of a Novel Dual Targeting Peptide for Human Glioma: From Simulation to Acting as Targeting Ligand.

Purpose: Receptor-mediated transcytosis (RMT) is a more specific, highly efficient, and reliable approach to crossing the blood-brain-barrier (BBB) and releasing the therapeutic cargos into the brain parenchyma.

Methods: Here, we introduced and characterized a human/mouse-specific novel leptin-derived peptide using , and experiments.

Results: Based on the bioinformatics analysis and molecular dynamics (MD) simulation, a 14 amino acid peptide sequence (LDP 14) was introduced and its interaction with leptin-receptor (ObR) was analyzed in comparison with an well known leptin-derived peptide, Lep 30.

Highly selective and sensitive colorimetric chemosensor using PVA/chitosan ion-imprinted nanofibers for copper ion detection and removal.

Herein, a highly efficient colorimetric chemosensor incorporating ion-imprinted electrospun nanofiber was developed for the removal and detection of Cu ions. In this regard, PVA/chitosan composites were used as the polymeric matrix, and 1-(2-pyridylazo)-2-naphthol was employed for complex formation. The prepared naked-eye sensor was characterized using Fourier transform infrared spectroscopy, energy-dispersive X-ray spectroscopy, scanning electron microscopy, atomic force microscopy, differential scanning calorimetry, thermogravimetric analysis, and X-ray diffraction analysis, revealing the morphological, structural, and molecular properties of the sensor.

Effect of an Experimental Resin-based Sealer (Resil) and AH-26 on Postoperative Pain: A Randomized Controlled Clinical Trial.

Introduction: One of the most common problems in endodontic treatments is post-treatment pain, and sealers might be one of the factors influencing the degree of pain following root canal therapy. The purpose of this study is to compare pain following endodontic treatment using an AH-26 resin sealer against the Resil experimental sealer in mandibular molars with irreversible pulpitis.

Materials And Methods: One hundred patients with irreversible pulpitis in the mandibular first or second molar were randomly divided into two groups (=50) based on the type of sealer applied.

Magnetic biochar as a revolutionizing approach for diverse dye pollutants elimination: A comprehensive review.

The term "biomass" encompasses all substances found in the natural world that were once alive or derived from living organisms or their byproducts. These substances consist of organic molecules containing hydrogen, typically oxygen, frequently nitrogen, and small amounts of heavy, alkaline earth and alkali metals. Magnetic biochar refers to a type of material derived from biomass that has been magnetized typically by adding magnetic components such as magnetic iron oxides to display magnetic properties.

Green and environmentally friendly architecture of starch-based ternary magnetic biocomposite (Starch/MIL100/CoFeO): Synthesis and photocatalytic degradation of tetracycline and dye.

The presence of tetracycline and dye as organic contaminants has led to the poisoning of wastewater. The aim of this study is to synthesize a novel biocomposite material by decorating natural starch polymer granules with metal-organic framework (MIL100) and cobalt ferrite magnetic (CoFeO) nanoparticles. The synthesized ternary magnetic biocomposite (Starch/MIL100/CoFeO) was used for the photocatalytic degradation of methylene blue (MB) and tetracycline (TCN) using LED visible light.

Clean synthesis of silver nanoparticles (AgNPs) on polyamide fabrics by Verbascum thapsus L. (mullein) extract: characterization, colorimetric, antibacterial, and colorfastness studies.

The production of antibacterial colored textiles using nanomaterials (NMs) has become an ideal goal from both a research and industrial perspective. In this study, the clean synthesis and characterization of silver nanoparticles (AgNPs) on polyamide fabrics were performed using mullein extract for the first time. Natural dyes were extracted from mullein leaves using an ultrasonic method, with an optimal amount of 15 g/L.