Enhancing FRET Efficiency through Synergistic Influences of Surfactants and Quantum Dots on Zinc Quinolate Complex-Dye Interactions.

Herein, we present a pioneering approach to enhancing Förster resonance energy transfer (FRET) efficiency through the synergistic integration of cetyltrimethylammonium bromide (CTAB) surfactants and ZnS quantum dots (QDs) within a zinc quinolate complex (ZQC)-dye (Rhodamine B: RhB) system. FRET efficiency is elevated from 13.1% to 49% with surfactants alone and further to an impressive 93.

Surface modification unleashes light emitting applications of APbX perovskite nanocrystals.

Engineering the surface of metal halide perovskite nanocrystals (MHPNCs) is crucial for optimizing their optical properties, repairing surface defects, enhancing quantum yield, and ensuring long-term stability. These enhancements make surface-engineered MHPNCs ideal for applications in light-emitting devices (LEDs), displays, lasers, and photodetectors, contributing to energy efficiency. This article delves into an introduction to MHPNCs, their structure and types, particularly the ABX type (where A represents monovalent organic/inorganic cations, B represents divalent metal ions mainly Pb metal, and X represents halide ions), synthesis methods, unique optical properties, surface modification techniques using various agents (particularly inorganic molecules/materials, organic molecules, polymers, and biomolecules) to tune optical properties and applications in the aforementioned light-emitting technologies, challenges and opportunities, including advantages and disadvantages of surface-modified APbX MHPNCs, and a summary and future outlook.

Surfactant-Assisted Förster Resonance Energy Transfer from a Quantum Dot Complex for Highly Stable White Light Emission.

Herein we report the fabrication of a surfactant modified quantum dot complex (S-QDC, having λ = 485 nm) nanocomposite (composed of cetyltrimethylammonium bromide surfactants and a zinc-quinolate complex attached ZnS quantum dot), the donor capability of S-QDC in Förster resonance energy transfer (FRET) with an acceptor organic molecule (λ = 573 nm), and finally their utilization in the FRET-based white light emission having features near to mid-day sunlight. The Förster distance, energy transfer efficiency, donor-acceptor distance, number of binding sites, and binding constant are evaluated to be 3.48 nm, 85.

Nanometal surface energy transfer (NSET) from biologically active heterocyclic ligands to silver nanoparticles induces enhanced antimicrobial activity against gram-positive bacteria.

Herein we report the formation of a nanometal surface energy transfer (NSET) pair between a donor biologically active heterocyclic luminescent ligand such as 3-(1,3-Dioxoisoindolin-2-yl)-N, N-dimethylpropan-1-ammonium perchlorate (SPNL; λ-408 nm) and an acceptor silver nanoparticle (Ag NP; λ-406 nm). When the SPNL ligand interacts with Ag NPs, the quenching in their luminescence intensity at 408 nm is noticed, with a Stern-Volmer constant of 0.8 × 10 M.