Category Ranking
98%
Total Visits
921
Avg Visit Duration
2 minutes
Citations
20
Article Abstract
We previously reported that the attempt to synthesize tetramethoxyindolo[3,2-]indole led to an undefined product. Now, it is confirmed that its instability is derived from the one-electron transfer from the tetramethoxyindolo[3,2-]indole derivatives to halogenated solvents under ultraviolet-visible (UV-vis) light irradiation, forming a stable indolo[3,2-]indole radical cation while causing the carbon-halogen (C-X, X = Cl, Br, I) bond scission.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/acs.joc.5c01360 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Revisiting the Synthesis of Tetramethoxyindolo[3,2-]indole Derivatives and the Study of Their Photoinduced Radical Formation in Halogenated Solvents.
J Org Chem
September 2025
Key Laboratory of Flexible Optoelectronic Materials and Technology, Ministry of Education, School of Optoelectronic Materials & Technology, Jianghan University, Wuhan 430056, P. R. China.
We previously reported that the attempt to synthesize tetramethoxyindolo[3,2-]indole led to an undefined product. Now, it is confirmed that its instability is derived from the one-electron transfer from the tetramethoxyindolo[3,2-]indole derivatives to halogenated solvents under ultraviolet-visible (UV-vis) light irradiation, forming a stable indolo[3,2-]indole radical cation while causing the carbon-halogen (C-X, X = Cl, Br, I) bond scission.
View Article and Find Full Text PDF