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For the pulsed data streams emitted by multiple signal sources that generate aliasing, traditional density clustering algorithms have the problems of poor clustering effect, heavy reliance on manual experience to set the parameters, and the need to carry out density clustering every time new data are input, resulting in a huge amount of computation. Therefore, an online density clustering algorithm based on the improved golden sine whale optimization is proposed. First, by adding new parameters to the density clustering algorithm, the neighborhood is changed from a single parameter Eps to a joint decision of the parameters Eps and θ, which avoids cross-cluster expansion by more flexibly delimiting the neighborhood range. The improved golden sine whale optimization algorithm is then used to obtain the optimal parameter solution of the DBSCAN algorithm. Finally, the idea of flow clustering is introduced to determine whether a pulse belongs to a valid library, an outlier library, or an inactive library by comparing the distance between the input pulse and each cluster center, effectively reducing the number of pulses required for analysis. The experiment proves that the algorithm improves the sorting accuracy by 57.7% compared to the DBSCAN algorithm and 37.8% compared to the WOA-DBSCAN algorithm.
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http://dx.doi.org/10.3390/s25165184 | DOI Listing |
Mol Psychiatry
September 2025
Department of Pharmacological and Biomolecular Sciences "Rodolfo Paoletti", Università degli Studi di Milano, Milan, Italy.
Early-life experiences shape neural networks, with heightened plasticity during the so-called "sensitive periods" (SP). SP are regulated by the maturation of GABAergic parvalbumin-positive (PV+) interneurons, which become enwrapped by perineuronal nets (PNNs) over time, modulating SP closure. Additionally, the opening and closing of SP are orchestrated by two distinct gene clusters known as "trigger" and "brake".
View Article and Find Full Text PDFInorg Chem
September 2025
Laboratoire de Chimie Physique Matière et Rayonnement (LCPMR), CNRS UMR 7614, Sorbonne Université (SU), 4 place Jussieu, Paris 75005, France.
The one-photon KV X-ray photoelectron spectra of Na and its hydrated clusters [Na(HO)] ( = 1-6) are dominated by the unusual 1s → 1s3s transition. KV spectroscopy also reveals a pronounced redistribution of the 1s → 1s3p transition cross sections, directly correlated with hydration number and molecular arrangement. Its intrinsic two-step nature, involving simultaneous core ionization and core excitation, enables detailed investigation of solvation-induced electronic structure changes, including dipole-forbidden excitations, core-valence charge transfer, and subtle 1s → V energy shifts.
View Article and Find Full Text PDFJ Am Chem Soc
September 2025
State Key Laboratory of Chemistry for NBC Hazards Protection, College of Chemistry, Fuzhou University, Fuzhou 350116, P. R. China.
The activation of methane and other gaseous hydrocarbons at low temperature remains a substantial challenge for the chemistry community. Here, we report an anaerobic photosystem based on crystalline borocarbonitride (BCN) supported Fe-O nanoclusters, which can selectively functionalize C-H bonds of methane, ethane, and higher alkanes to value-added organic chemicals at 12 °C. Scanning transmission electron microscopy and X-ray absorption spectroscopy corroborated the ultrafine FeOOH and FeO species in Fe-O clusters, which enhanced the interfacial charge transfer/separation of BCN as well as the chemisorption of methane.
View Article and Find Full Text PDFJ Phys Chem Lett
September 2025
Faculty of Chemistry, Wrocław University of Science and Technology, Wyb. Wyspiańskiego 27, PL-50370 Wrocław, Poland.
Computer simulations play an essential role in the interpretation of experimental multiphoton absorption spectra. In addition, models derived from theory allow for the establishment of "structure-property" relationships. This work contributes to these efforts and presents the results of an analysis of two- and three-photon absorptions for a set comprising 450 conjugated molecules performed at the CAM-B3LYP/aug-cc-pVDZ level.
View Article and Find Full Text PDFRMD Open
September 2025
Department of Rheumatology and Department of Internal Medicine, Ghent University Hospital, Unit for Molecular Immunology and Inflammation, Flemish Institute for Biotechnology, Inflammation Research Center, University of Ghent, Ghent, Belgium.
Objectives: To evaluate whether patients with systemic lupus erythematosus (SLE) have different nailfold videocapillaroscopy (NVC) findings compared with healthy controls (HCs) and whether there is an association between NVC abnormalities and disease activity, clinical and/or laboratory features in SLE.
Methods: This is an observational, multicentre, international, matched case-control study. 381 subjects (203 patients with SLE and 178 HCs) were enrolled from 16 centres in 10 countries.