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Article Abstract
The incorporation of three terdentate 2,6-bis-triazolyl-pyridine units on a calix[4]arene gives a preorganized lipophilic ligand with enhanced efficiency in binding trivalent actinides over lanthanides. Combined time-resolved laser-induced fluorescence spectroscopy, and 1D and H-N HMQC NMR investigations allowed to propose the structures of the complexes and to provide insights into the actinide selectivity.
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A preorganized triarmed bis-triazolylpyridine-calix[4]arene with high affinity and selectivity for minor actinides for nuclear waste treatment.
Chem Commun (Camb)
August 2025
Dept. of Chemistry, Life Sciences and Environmental Sustainability, Università di Parma, Parco Area delle Scienze 17/a, 43124 Parma, Italy.
The incorporation of three terdentate 2,6-bis-triazolyl-pyridine units on a calix[4]arene gives a preorganized lipophilic ligand with enhanced efficiency in binding trivalent actinides over lanthanides. Combined time-resolved laser-induced fluorescence spectroscopy, and 1D and H-N HMQC NMR investigations allowed to propose the structures of the complexes and to provide insights into the actinide selectivity.
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