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The directional and spectral control of thermal emission with a tunable angular range is essential for realizing next-generation smart thermal emitters. However, existing photonic strategy-based thermal emitters manage thermal emission only over a fixed angular range. Here, we present a lossless chalcogenide phase change material (PCM)-based tunable multilayer structure as a thermal emitter for actively regulating angular selectivity in thermal emission. We develop a tunable multilayer stack with a thickness of 1.35 μm by layering alternating thin films of SiO and a high-crystallization-temperature PCM, such as SbS. The principle underlying the proposed tunable directional control of thermal emission relies on the tunable Brewster mode within the SiO-SbS multilayer cavity. For -polarized light, the cavity exhibits maximum emissivity across a broad spectral band (10-18 μm) around the Brewster angle. In particular, a peak emissivity of over 95% is achieved in this broad spectral band at the Brewster angle. The angular range of maximum thermal emission can be tuned through the non-volatile structural phase transition property of SbS, while maintaining a constant spectral bandwidth. Moreover, we demonstrate electrically controlled thermal emission using a microheater-integrated SbS-SiO multilayer cavity. This photonic structure could serve as a versatile, tunable, lithography-free platform to dynamically control the angular range of directional thermal emission and emissivity for emerging applications of thermal emitters.
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http://dx.doi.org/10.1039/d5nh00367a | DOI Listing |
Adv Mater
September 2025
State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, 130012, P. R. China.
Helicene-based circularly polarized luminescence (CPL) materials suffer from severely low color purity in circularly polarized organic light-emitting diodes (CP-OLEDs). Here, a novel molecular engineering strategy is introduced by replacing helicene containing continuous fused benzene rings with a multiple resonance (MR) framework comprising discontinuous fused benzene rings. This approach effectively suppresses high-frequency C─C bond stretching vibrations and enhances short-range charge transfer, enabling high color purity, CPL activity, and efficient thermally activated delayed fluorescence (TADF).
View Article and Find Full Text PDFRSC Adv
September 2025
Otto-von-Guericke-University Magdeburg, Chemical Institute, Chair for Industrial Chemistry Universitätsplatz 2 39106 Magdeburg Germany
This work elucidates the thermo-kinetics of the thermal conversion of cameroonian kaolin to metakaolin as the main product. The thermokinetical parameters (activation energy and pre-exponential factor ) for the kaolin conversion were calculated using model-free methods, the Kissinger-Akahira-Sunrose (KAS) and the Flynn-Wall-Ozawa (FWO) method, and differential methods (Kissinger and Ozawa) additionally including iterative procedures for KAS and FWO methods (KAS-Ir; FWO-Ir). The cameroonian kaolin was heat-treated using three different heating rates, 5, 20 and 40 K min, leading to metakaolin samples named MK-(5), MK-(20) and MK-(40).
View Article and Find Full Text PDFEnviron Monit Assess
September 2025
Department of Environment and Life Science, KSKV Kachchh University, Bhuj, Gujarat, 370 001, India.
India's energy demand increased by 7.3% in 2023 compared to 2022 (5.6%), primarily met by coal-based thermal power plants (TPPs) that contribute significantly to greenhouse gas emissions.
View Article and Find Full Text PDFSci Total Environ
September 2025
Politecnico di Milano, Department of Chemistry, Materials and Chemical Engineering, "Giulio Natta" - Piazza Leonardo da Vinci 32, 20133, Milano, Italy.
The outdoor storage of wood chips, used in biomass thermal power plants, may lead to different diffuse gaseous emissions. These emissions can contain different molecules, often with a non-negligible odour potential. Despite this need, these solid area sources are particularly complex to be characterised, due to their very high heterogeneity determined by a complex phenomenon of self-heating.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
September 2025
Vellore Institute of Technology, Vellore, 632014, Tamil Nadu, India.
The significant global energy consumption strongly emphasizes the crucial role of net-zero or green structures in ensuring a sustainable future. Considering this aspect, incorporating thermal insulation materials into building components is a well-accepted method that helps to enhance thermal comfort in buildings. Furthermore, integrating architectural components made from solid refuse materials retrieved from the environment can have significant environmental benefits.
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