98%
921
2 minutes
20
A free energy density for the nematic phase with two symmetry elements - the director, , and the vector defining the helix direction, - can be constructed as an extension of the Frank free energy. This formulation has already proven effective in demonstrating that the phase transition between the conventional nematic phase and the twist-bend nematic phase is of second order, characterized by a finite wave vector. In this work, we theoretically investigate the possibility that new periodic phases with finite wave vectors may be energetically favored over uniform structures within the framework of this elastic model. We show that splay-twist-like periodic structures naturally emerge from this theoretical approach. Furthermore, we demonstrate that the existence of a critical wave vector, which determines the periodicity of the non-uniform structure, depends on the elastic parameters, the sample thickness, and the anchoring energy strengths. A key role is played by the elastic constant that couples the nematic director to the helical axis: a distinctive feature of these materials. The splay-twist transition from the uniform nematic phase occurs only when the magnitude of the coupling elastic constant exceeds a threshold value. In this study, we specifically treat the case of a sample with symmetrical interfaces.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1039/d5sm00565e | DOI Listing |
Proc Natl Acad Sci U S A
September 2025
Geballe Laboratory for Advanced Materials, Stanford University, Stanford, CA 94305.
The iron-based high-[Formula: see text] superconductors (SCs) exhibit rich phase diagrams with intertwined phases, including magnetism, nematicity, and superconductivity. The superconducting [Formula: see text] in many of these materials is maximized in the regime of strong nematic fluctuations, making the role of nematicity in influencing the superconductivity a topic of intense research. Here, we use the AC elastocaloric effect (ECE) to map out the phase diagram of Ba(FeCo)As near optimal doping.
View Article and Find Full Text PDFLangmuir
September 2025
Centre québécois sur les matériaux fonctionnels/Quebec Centre for Advanced Materials (CQMF/QCAM), Chemistry Department, 801 Sherbrooke St. W., Montreal, Québec H3A 0B8, Canada.
Poly(γ-stearyl-l-glutamate) (PSLG) is a semiflexible synthetic polypeptide that forms both thermotropic and lyotropic liquid crystal (LC) phases. We previously showed that spherical nanoparticles (NPs) decorated with another semiflexible helical polymer, poly(hexyl isocyanate), form lyotropic nematic rather than cubic LC phases. In this work, PSLG ligands for functionalizing 4 nm ZrO NPs were prepared via N-carboxyanhydride ring-opening polymerization.
View Article and Find Full Text PDFAdv Mater
September 2025
Soft Matter Optics Group, Wroclaw University of Science and Technology, Wyb. Wyspianskiego 27, Wroclaw, 50-370, Poland.
Nematic Liquid Crystals (LCs), noted for their simple molecular alignment and broad use in optoelectronics, remain unmodified for over a century. However, in 2017, a unique polar phase, the ferroelectric nematic (N), is confirmed. Subsequently, in 2024, the revolutionary spontaneous mirror symmetry breaking of ferroelectric twist-bend nematic chiral structures (N phase) is demonstrated.
View Article and Find Full Text PDFSmall
September 2025
Faculty of Electrical Engineering, Częstochowa University of Technology, Al. Armii Krajowej 17, Częstochowa, 42-200, Poland.
Bent-core nematic liquid crystals exhibit unique properties, including giant flexoelectricity and polar electro-optic responses, making them ideal for energy conversion and electro-optic applications. When confined in nanopores, they can stabilize chiral nanostructures, enhance polar order, and enable defect-driven switching - offering potential in nanofluidics, sensing, and adaptive optics. The thermotropic ordering of the bent-core dimer CB7CB confined in anodic aluminum oxide (AAO) and silica membranes with precisely engineered cylindrical nanochannels - ranging from just a few nanometers to several hundred nanometers-is examined.
View Article and Find Full Text PDFACS Nano
September 2025
Hefei National Research Center for Physical Sciences at the Microscale, CAS Key Laboratory of Strongly-Coupled Quantum Matter Physics, Department of Physics, University of Science and Technology of China, Hefei, Anhui 230026, China.
As a versatile platform for exploring exotic quantum phases, moiré superlattices, ranging from twisted graphene to twisted transition metal dichalcogenides, have been intensively studied. In this work, based on exact diagonalization and Hartree-Fock mean-field calculations, the interaction-driven topological phases are investigated in hole-doped twisted bilayer MoS at the high filling factor = 3. Besides the nematic insulator and quantum anomalous Hall phases, the topological Wigner molecule crystal (TWMC) phase is found in the phase diagram.
View Article and Find Full Text PDF