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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC12343012 | PMC |
| http://dx.doi.org/10.1093/plphys/kiaf332 | DOI Listing |
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Clusters composed of heavy elements, particularly actinides, provide a compelling platform for exploring unconventional bonding and the role of relativistic effects in electronic structure and stability. In this study, we critically reassess the -symmetric PaB cluster, previously claimed to exhibit double Möbius-Craig aromaticity through delocalization of 4σ and 4π electrons. Our potential energy surface (PES) analysis disproves this assignment by showing that the structure is a higher-energy isomer; the most stable form adopts a distorted tetrahedral structure.
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