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Article Abstract
A novel, durable heterogeneous magnesium-supported catalyst, IRMOF-3@Di(2-pyridyl) ketone@Mg(II) (Di(2-pyridyl) ketone: Di-2pyk), was effectively synthesized using a convenient approach and fully characterized utilizing chemo-physical analysis techniques such as powder X-ray diffraction analysis, attenuated total reflection infrared spectroscopy, field emission scanning electron microscopy with energy-dispersive spectroscopy, transmission electron microscopy, CHN analysis, inductively coupled plasma optical emission spectroscopy, thermogravimetric analysis and Brunauer-Emmett-Teller measurements. This metal-organic framework-based nanocatalyst displayed excellent catalytic behaviour in chemoselective hydrogenation of five biomass-based carbonyl compounds of furfural, cinnamaldehyde, levulinic acid, vanillin and citral in addition to a variety of aliphatic, aromatic, and α,β-unsaturated aldehydes and ketones at room temperature in water in the presence of sodium borohydride as a mild and safe hydrogen source reagent. The leaching and reusability experiments of this catalyst exhibited stability and reactivity after four runs.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC12326088 | PMC |
| http://dx.doi.org/10.1098/rsos.242257 | DOI Listing |
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