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Article Abstract
The modular assembly for high-nuclearity clusters is crucial for elucidating structure-activity relationships and broadening their functional applications. Herein, we prepared a novel pebble-type giant polyoxomolybdate cage NaH[MoMoO(OH)]·130HO {} hydrothermal methods. The {} cage features an elliptical molybdenum wheel {Mo} capped by three different small molybdenum building blocks with a flat inner cavity (6 Å). Moreover, {} exhibits a proton conductivity of 5.14 × 10 S·cm at 95 °C under 98% relative humidity.
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Assembly of a Pebble-Type Giant Polyoxometalate Cage {Mo} for Proton Conduction.
Inorg Chem
August 2025
Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Molecular Sciences, Henan University, Kaifeng, Henan 475004, P. R. China.
The modular assembly for high-nuclearity clusters is crucial for elucidating structure-activity relationships and broadening their functional applications. Herein, we prepared a novel pebble-type giant polyoxomolybdate cage NaH[MoMoO(OH)]·130HO {} hydrothermal methods. The {} cage features an elliptical molybdenum wheel {Mo} capped by three different small molybdenum building blocks with a flat inner cavity (6 Å).
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