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We report the fundamental theoretical framework of the ellipsoid-dipole model and its applicability in quantifying the pairwise dipolar energy between ellipsoids with different sizes, aspect ratios, and magnetic properties. Additionally, we discuss the limitations of the model and its potential for describing interacting ellipsoids under various field conditions for both established and emerging applications. We analyze the dipolar interaction energy of suspensions composed of different pairs of magnetic ellipsoids, including permanently magnetized ellipsoids, paramagnetic ellipsoids, diamagnetic ellipsoids, and mixtures of them. We validate the results of the ellipsoid-dipole model and the corresponding pairwise dipolar interaction energy against those produced by the point-dipole approximation. Furthermore, we quantify the relative equilibrium positions and orientations of different ellipsoid pairs in a uniform magnetic field. The article shows that the ellipsoid-dipole model offers a wide range of possibilities for predicting and engineering colloidal suspensions composed of binary ellipsoids and for enhancing current applications.
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http://dx.doi.org/10.1039/d5sm00438a | DOI Listing |
Soft Matter
August 2025
Department of Chemical and Materials Engineering, The University of Alabama in Huntsville, Huntsville, AL 35899, USA.
We report the fundamental theoretical framework of the ellipsoid-dipole model and its applicability in quantifying the pairwise dipolar energy between ellipsoids with different sizes, aspect ratios, and magnetic properties. Additionally, we discuss the limitations of the model and its potential for describing interacting ellipsoids under various field conditions for both established and emerging applications. We analyze the dipolar interaction energy of suspensions composed of different pairs of magnetic ellipsoids, including permanently magnetized ellipsoids, paramagnetic ellipsoids, diamagnetic ellipsoids, and mixtures of them.
View Article and Find Full Text PDFSoft Matter
August 2024
Department of Chemical and Materials Engineering, The University of Alabama in Huntsville, Huntsville, AL 35899, USA.
We report the effect of shape anisotropy and material properties on the directed assembly of binary suspensions composed of magnetizable ellipsoids. In a Monte Carlo simulation, we implement the ellipsoid-dipole model to calculate the pairwise dipolar interaction energy as a function of position and orientation. The analysis explores dilute suspensions of paramagnetic and diamagnetic ellipsoids with different aspect ratios in a superparamagnetic medium.
View Article and Find Full Text PDFSoft Matter
January 2023
Department of Chemical and Materials Engineering, The University of Alabama in Huntsville, Huntsville, AL 35899, USA.
We report the effect of the dipole-dipole interaction and shape anisotropy in suspensions of permanently magnetized anisotropic particles. We quantify the dipolar interaction energy using an ellipsoid-dipole model to describe particles with similar or dissimilar shapes. The expression captures the physics of the point-dipole interaction energy between uniformly magnetized spherical particles.
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