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The escalating environmental concerns associated with plastic waste, particularly Low-Density Polyethylene (LDPE), have spurred research into sustainable recycling strategies. Pyrolysis has been developed as a viable technique for transforming LDPE into appreciated by-products, including carbon powder, which holds potential for advanced material applications. This study investigates the extraction of carbon powder from LDPE via pyrolysis and its subsequent utilization in composite laminates.•Araldite LY 556 and Aradur HY 951 epoxy resins are used to create the laminates, and carbon and kevlar fiber reinforcement are added in different weight fractions of 0 to 30 % in the intervals of 10 % of carbon char generated from LDPE.•Tensile strength (ASTM D638), flexural strength (ASTM D790), X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR) and scanning electron microscopy (SEM) are used to do a thorough assessment of mechanical and structural features.•Incorporation of LDPE-derived carbon char significantly enhanced mechanical properties of epoxy-based laminates. At 30 wt % char, tensile strength increased by 75 % in carbon and 129 % in Kevlar composites, while flexural strength improved by 94 % and 196 %, respectively. SEM, XRD, and FTIR analyses confirmed improved interfacial adhesion, structural integrity, and filler stability, demonstrating char's effectiveness as a sustainable reinforcement.
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http://dx.doi.org/10.1016/j.mex.2025.103449 | DOI Listing |
Langmuir
September 2025
Engineering Technology Research Center of Preparation and Application of Industrial Ceramics of Anhui Province, Engineering Research Center of High-frequency Soft Magnetic Materials and Ceramic Powder Materials of Anhui Province, School of Chemistry and Material Engineering, Chaohu University, Chaoh
In this study, a MoC-MoO@NCrGO-900 composite catalyst comprising two-dimensional nitrogen-doped reduced graphene oxide (NCrGO) and ultrasmall molybdenum carbide-molybdenum dioxide (MoC-MoO) heterojunctions was synthesized. The optimized catalyst exhibited an outstanding oxidative desulfurization (ODS) performance. Specifically, a model oil containing 4000 ppm sulfur was completely desulfurized within 30 min, with a desulfurization efficiency of 98.
View Article and Find Full Text PDFJ Am Chem Soc
September 2025
Beijing National Laboratory for Molecular Sciences, CAS Laboratory of Colloid and Interface and Thermodynamics, Center for Carbon Neutral Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.
CO electroreduction to produce fuels and chemicals is of great significance. Molecular catalysts offer valuable advantages in light of their well-defined active sites and tunable structural and electronic properties. However, their stability is often compromised by rigid conjugated structures.
View Article and Find Full Text PDFACS Omega
September 2025
School of Chemical and Materials Engineering (SCME), National University of Sciences & Technology (NUST), H-12, Islamabad 44000, Pakistan.
In this study, we present an indigenous approach to enhancing the properties of Pb-(ZrTi)-O by synthesizing it from β-PbO obtained from spent lead-acid batteries. Initially, β-PbO, orthorhombic massicot, was produced by two-step heating, and 99.9% lead powder was derived from recovered lead-acid batteries at 700 °C.
View Article and Find Full Text PDFACS Omega
September 2025
Department of Anthropology, Texas A&M University, College Station, Texas United States.
Following their defeat in the Texas Revolution of 1836, the Mexican Army disabled and buried cannons used in the defense of the Alamo. Rediscovered in 1852, 13 of these cannons have since journeyed through private collections and public exhibits before arriving at the Alamo. Among them is a bronze 4-pounder cannon, thought to have seen action during the battle itself.
View Article and Find Full Text PDFACS Omega
September 2025
Institut de Chimie et Procédés pour l'Energie, l'Environnement et la Santé (ICPEES), UMR-7515 CNRS-Université de Strasbourg, 25 rue Becquerel, 67087 Strasbourg, France.
For photodetection applications using 3D hybrid perovskites (HPs), dense and thick films or compacted powders in wafer form are needed and generally require large amounts of HPs. HPs are also often combined with a graphene/carbon layer to improve their conductivity. Among HP synthesis methods, mechanosynthesis, a green synthesis method, provides a large amount of powders, which are furthermore easily densified in compact wafers due to their mechanical activation.
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