Metal-organic framework containing Co(μ-OH)-based kagomé layers showing long-range weak ferromagnetic ordering.

Chem Commun (Camb)

State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023, P. R. China.

Published: August 2025


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Article Abstract

The compounds Co(OH)(5-cnapp)(HO) (1) and Co(OH)(4-cnapp)(HO)·12HO (2) obtained using positionally isomeric phosphonic acids (5-/4-cnappH) have 3D framework structures. Compound 1 contains a distorted Co(μ-OH)-based kagomé layer and shows long-range weak ferromagnetic ordering below 30 K without significant spin frustration.

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Source
http://dx.doi.org/10.1039/d5cc02658jDOI Listing

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