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Directed self-assembly (DSA) lithography, a cutting-edge technology based on the self-assembly of block copolymers (BCPs), has received significant attention in recent years. Combining DSA with established lithography technologies, such as extreme ultraviolet (EUV), deep ultraviolet (DUV), electron beam lithography, and nanoimprint lithography, significantly enhances the resolution of target patterns and device density. Currently, there are two commonly used methods in DSA: graphoepitaxy, employing lithographically defined topographic templates to guide BCP assembly, and chemoepitaxy, utilizing chemically patterned surfaces with precisely controlled interfacial energies to direct nanoscale phase segregation. Through novel DSA lithography technology, nanoscale patterns with smaller feature sizes and higher densities can be obtained, realizing the miniaturization of hole and line patterns and pitch multiplication and improving the roughness and local critical dimension uniformity (LCDU). It is gradually becoming one of the most promising and advanced lithography techniques. DSA lithography technology has been applied in logic, memory, and optoelectronic device fabrications.
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http://dx.doi.org/10.3390/mi16060667 | DOI Listing |
ACS Appl Mater Interfaces
August 2025
School of Information Science and Technology, Fudan University, Shanghai 200433, China.
Achieving pattern density multiplication through direct self-assembly (DSA) is a viable path to increasing manufacturing throughput and reducing costs in photolithographic manufacturing. However, as the density multiplication factor increases, current process flows face challenges in achieving defect-free ordered arrangements with the experimentally realized multiplication factors being limited. This study proposes an innovative method to guide cylindrical PS--PMMA, achieving a maximum multiplication factor of 48×.
View Article and Find Full Text PDFMicromachines (Basel)
May 2025
Beijing Superstring Academy of Memory Technology, Beijing 100176, China.
Directed self-assembly (DSA) lithography, a cutting-edge technology based on the self-assembly of block copolymers (BCPs), has received significant attention in recent years. Combining DSA with established lithography technologies, such as extreme ultraviolet (EUV), deep ultraviolet (DUV), electron beam lithography, and nanoimprint lithography, significantly enhances the resolution of target patterns and device density. Currently, there are two commonly used methods in DSA: graphoepitaxy, employing lithographically defined topographic templates to guide BCP assembly, and chemoepitaxy, utilizing chemically patterned surfaces with precisely controlled interfacial energies to direct nanoscale phase segregation.
View Article and Find Full Text PDFJ Chem Phys
March 2025
Department of Advanced Optical and Microelectronic Equipment, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China.
Self-consistent field theory (SCFT) is a powerful polymer field-theoretic simulation tool that plays a crucial role in the study of block copolymer (BCP) self-assembly. However, the computational cost of implementing SCFT simulations is comparatively high, particularly in computationally demanding applications where repeated forward simulations are needed. Herein, we propose a deep learning-based method to accelerate the SCFT simulations.
View Article and Find Full Text PDFACS Macro Lett
August 2024
Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology (KAIST), 291 Daehak-ro, Yuseong-gu, Daejeon 34141, Republic of Korea.
Although extreme ultraviolet lithography (EUVL) has emerged as a leading technology for achieving high quality sub-10 nm patterns, the insufficient pattern height of photoresist patterns remains a challenge. Directed self-assembly (DSA) of block copolymers (BCPs) is expected to be a complementary technology for EUVL due to its ability to form periodic nanostructures. However, for a combination with EUV patterns, it is essential to develop advanced BCP systems that are suited to inorganic-containing EUV photoresists and offer improved resolution limits, pattern quality, and etch resistance.
View Article and Find Full Text PDFACS Appl Mater Interfaces
June 2024
Key Laboratory of Specially Functional Polymeric Materials and Related Technology (Ministry of Education), School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China.
We leveraged the potential of high χ-low block copolymer (BCP), namely, poly[2-(perfluorobutyl) ethyl methacrylate]--poly(2-vinylpyridine) (P2PFBEMA--P2VP), and demonstrated its utility in next-generation nanomanufacturing. By combining molecular dynamics simulations with experiments, the χ value was calculated to be as high as 0.4 (at 150 °C), surpassing similar structures.
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