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Article Abstract
Rh(III)-catalyzed oxidative [3+2] annulation between arylboron reagents and azabicyclic olefins is presented. This system offers an effective example of transmetalation-promoted C-H activation using easily available arylboron reagents, which provides a series of -fused dihydrocarbazoles both and functionalization of the arylboron reagents. Importantly, this annulation reaction circumvents the reliance on a directing group in the arene ring.
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