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Epistemic emotions, such as curiosity and interest, drive the inquiry process. This study proposes a novel formulation of these emotions using two types of information gain derived from the principle of free energy minimization: Kullback-Leibler divergence (KLD), representing free energy reduction through recognition, and Bayesian surprise (BS), representing free energy reduction via Bayesian updating. Conventional Gaussian models predict an infinite divergence in information gain (KLD and BS) as prediction error increases, which contradicts the known limits of human cognitive resources. The key novelty of this study lies in a simple yet impactful modification: incorporating a uniform distribution into the Gaussian likelihood function to model neural activity under conditions of large prediction error. This modification yields an inverted U-shaped relationship between prediction error and both KLD and BS, producing a finite peak in information gain that better reflects cognitive realism. Based on this convexity, we propose that alternating the maximization of BS and KLD generates an ideal inquiry cycle that fluctuates around an optimal arousal level, with curiosity and interest driving this process. We further analyze how prediction uncertainty (prior variance) and observation uncertainty (likelihood variance) affect the peak of information gain. The results suggest that greater prediction uncertainty (reflecting open-mindedness) and lower observation uncertainty (indicating focused observation) promote higher information gains through broader exploration. This mathematical framework integrates the brain's free energy principle with arousal potential theory, providing a unified explanation of the Wundt curve as an information gain function and proposing an ideal inquiry process driven by epistemic emotions.
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http://dx.doi.org/10.3389/fpsyg.2025.1438080 | DOI Listing |
J Am Chem Soc
September 2025
Shenzhen Key Laboratory of Micro/Nano-Porous Functional Materials (SKLPM), SUSTech-Kyoto University Advanced Energy Materials Joint Innovation Laboratory (SKAEM-JIL), Guangdong-Hongkong-Macao Joint Laboratory for Photonic-Thermal-Electrical Energy Materials and Devices and Department of Chemistry, S
Postsynthetic modification (PSM) is a powerful strategy for tailoring the structure and functionality of covalent organic frameworks (COFs). In this work, we present a novel enzymatic PSM strategy for functional group engineering within COFs. By taking advantage of enzymatic catalysis, 2-hydroxyethylthio (-S-EtOH) and ethylthio (-S-Et) groups were covalently implanted within the COF pore channels with high grafting efficiency under ambient aqueous conditions, highlighting the mild, efficient, and ecofriendly nature of this approach.
View Article and Find Full Text PDFNanoscale
September 2025
Department of Chemistry, Material Science Lab, Annamalai University, Annamalai Nagar, Tamil Nadu 608002, India.
The transition to a net-zero carbon economy hinges on the development of sustainable, efficient, and economically viable energy technologies. Here, we present a green, electricity-free auto-combustion synthesis of a multifunctional FeNi@MnO@C electrocatalyst, demonstrating outstanding performance for OER, HER, OWS, UOR, UOS, and OWS in alkaline seawater with a required potential of 1.45, 0.
View Article and Find Full Text PDFJ Comput Chem
September 2025
Department of Electrical and Electronic Engineering, Begum Rokeya University, Rangpur, Bangladesh.
This study presents a comprehensive first-principles and device-performance investigation of alkali metal-based anti-perovskites ZBrO (Z = K, Rb, Cs, and Fr) for advanced optoelectronic and photovoltaic applications. Using density functional theory (DFT) with GGA-PBE and mGGA-rSCAN functionals, we analyzed the structural, electronic, optical, mechanical, phonon, population, and thermoelectric properties of these compounds. All ZBrO materials exhibit direct band gaps and strong optical absorption in the visible-UV spectrum.
View Article and Find Full Text PDFNutr Res Rev
September 2025
Institute of Animal Science, University of Hohenheim, Stuttgart, Germany.
Reducing crude protein in amino acid-adequate diets for broiler chickens is effective in reducing nitrogenous emissions and competition for resources between the food and feed sectors. This review provides a comprehensive analysis of the literature on the relevance of nonessential amino acids in low-protein diets for broiler chickens. Glycine and serine, due to their interconvertibility summarized as glycine equivalents ( ), limit growth when dietary crude protein is reduced below 19% in up to 3-week-old birds.
View Article and Find Full Text PDFBiophys J
September 2025
Key Laboratory of Hydrodynamics (Ministry of Education), Department of Engineering Mechanics, School of Ocean and Civil Engineering, Shanghai Jiao Tong University, Shanghai 200240, China. Electronic address:
The interplay between subcellular adhesion dynamics and cellular-scale deformations under shear flow drives key physiological and pathological processes. While both bond kinetics and fluid-cell interactions have been extensively studied in rolling adhesion, how bond characteristics quantitatively determine cellular velocity distributions remains unclear. In this study, we systematically investigate how force-free bond kinetics and intrinsic mechanical properties govern rolling adhesion dynamics, using macroscopic velocity distributions as a reference.
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